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Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, stucture and diastereomeric transformations

Remir Grigorevich Kostyanovsky 1
Remir Grigorevich Kostyanovsky
, 
Volker Schurig 2
Volker Schurig
, 
Oliver Trapp 2
Oliver Trapp
, 
Konstantin Alexandrovich Lyssenko 3
Konstantin Alexandrovich Lyssenko
, 
Boris Borisovich Averkiev 3
Boris Borisovich Averkiev
, 
Gulnara Konstantinovna Kadorkina 1
Gulnara Konstantinovna Kadorkina
, 
Alexander V Prosyanik 4
Alexander V Prosyanik
, 
Vasily Remirovich Kostyanovsky 1
Vasily Remirovich Kostyanovsky
10.1070/MC2002v012n04ABEH001612
Published 2002-09-12
Communication , Volume 12, Issue 4, 137-140
17
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Kostyanovsky R. G. et al. Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, stucture and diastereomeric transformations // Mendeleev Communications. 2002. Vol. 12. No. 4. pp. 137-140.
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Kostyanovsky R. G., Schurig V., Trapp O., Lyssenko K. A., Averkiev B. B., Kadorkina G. K., Prosyanik A. V., Kostyanovsky V. R. Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, stucture and diastereomeric transformations // Mendeleev Communications. 2002. Vol. 12. No. 4. pp. 137-140.
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TY - JOUR
DO - 10.1070/MC2002v012n04ABEH001612
UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n04ABEH001612
TI - Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, stucture and diastereomeric transformations
T2 - Mendeleev Communications
AU - Kostyanovsky, Remir Grigorevich
AU - Schurig, Volker
AU - Trapp, Oliver
AU - Lyssenko, Konstantin Alexandrovich
AU - Averkiev, Boris Borisovich
AU - Kadorkina, Gulnara Konstantinovna
AU - Prosyanik, Alexander V
AU - Kostyanovsky, Vasily Remirovich
PY - 2002
DA - 2002/09/12
PB - Mendeleev Communications
SP - 137-140
IS - 4
VL - 12
ER -
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@article{2002_Kostyanovsky,
author = {Remir Grigorevich Kostyanovsky and Volker Schurig and Oliver Trapp and Konstantin Alexandrovich Lyssenko and Boris Borisovich Averkiev and Gulnara Konstantinovna Kadorkina and Alexander V Prosyanik and Vasily Remirovich Kostyanovsky},
title = {Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, stucture and diastereomeric transformations},
journal = {Mendeleev Communications},
year = {2002},
volume = {12},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n04ABEH001612},
number = {4},
pages = {137--140},
doi = {10.1070/MC2002v012n04ABEH001612}
}
MLA
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Kostyanovsky, Remir Grigorevich, et al. “Chiral 1-alkoxyaziridines: resolution, nitrogen inversion, stucture and diastereomeric transformations.” Mendeleev Communications, vol. 12, no. 4, Sep. 2002, pp. 137-140. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n04ABEH001612.

Abstract

The resolution of enantiomers by chiral chromatography and the determination of nitrogen inversion activation parameters by dynamic chromatography have been carried out for aziridines 1–3; the structures of aziridines 4–7 have been studied; the complete diastereomeric transformation of (S,R)-(+)-8a into (R,R)-(–)-8b has been performed, and the conglomerate of high-melting diastereomer (±)-9 has been found.

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