Home / Publications / Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation

Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation

Ivan Sergeyevich Orlov 1
Ivan Sergeyevich Orlov
, 
Anna Anisimovna Moiseeva 2
Anna Anisimovna Moiseeva
, 
Kim Petrovich Butin 2
Kim Petrovich Butin
, 
Lawrence R Sita 3
Lawrence R Sita
, 
Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
, 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
10.1070/MC2002v012n04ABEH001601
Published 2002-09-12
Communication , Volume 12, Issue 4, 125-126
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Orlov I. S. et al. Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation // Mendeleev Communications. 2002. Vol. 12. No. 4. pp. 125-126.
GOST all authors (up to 50) Copy
Orlov I. S., Moiseeva A. A., Butin K. P., Sita L. R., Egorov M. P., Nefedov O. M. Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation // Mendeleev Communications. 2002. Vol. 12. No. 4. pp. 125-126.
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TY - JOUR
DO - 10.1070/MC2002v012n04ABEH001601
UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n04ABEH001601
TI - Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation
T2 - Mendeleev Communications
AU - Orlov, Ivan Sergeyevich
AU - Moiseeva, Anna Anisimovna
AU - Butin, Kim Petrovich
AU - Sita, Lawrence R
AU - Egorov, Mikhail Petrovich
AU - Nefedov, Oleg Matveevich
PY - 2002
DA - 2002/09/12
PB - Mendeleev Communications
SP - 125-126
IS - 4
VL - 12
ER -
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@article{2002_Orlov,
author = {Ivan Sergeyevich Orlov and Anna Anisimovna Moiseeva and Kim Petrovich Butin and Lawrence R Sita and Mikhail Petrovich Egorov and Oleg Matveevich Nefedov},
title = {Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation},
journal = {Mendeleev Communications},
year = {2002},
volume = {12},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n04ABEH001601},
number = {4},
pages = {125--126},
doi = {10.1070/MC2002v012n04ABEH001601}
}
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Orlov, Ivan Sergeyevich, et al. “Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation.” Mendeleev Communications, vol. 12, no. 4, Sep. 2002, pp. 125-126. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n04ABEH001601.

Abstract

The radical anion of di(2,6-diethylphenyl)stannylene (Ar2Sn) has been generated by the electrochemical reduction of cyclotristannane cyclo-(Ar2Sn)3, and the electrochemical oxidation of cyclo-(Ar2Sn)3 resulted in Sn–Sn bond cleavage with the formation of the radical cation of tristannane.

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