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Preparation of 1,2-bis(3,4-dicyanophenoxymethyl)benzene and the binuclear zinc phthalocyanine derived from it

Alexander Yurevich Tolbin 1
Alexander Yurevich Tolbin
, 
Alexey V Ivanov 2
Alexey V Ivanov
, 
Larisa Godvigovna Tomilova 1
Larisa Godvigovna Tomilova
, 
Nikolai Serafimovich Zefirov 2
Nikolai Serafimovich Zefirov
10.1070/MC2002v012n03ABEH001573
Published 2002-07-05
Communication , Volume 12, Issue 3, 96-97
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Tolbin A. Y. et al. Preparation of 1,2-bis(3,4-dicyanophenoxymethyl)benzene and the binuclear zinc phthalocyanine derived from it // Mendeleev Communications. 2002. Vol. 12. No. 3. pp. 96-97.
GOST all authors (up to 50) Copy
Tolbin A. Y., Ivanov A. V., Tomilova L. G., Zefirov N. S. Preparation of 1,2-bis(3,4-dicyanophenoxymethyl)benzene and the binuclear zinc phthalocyanine derived from it // Mendeleev Communications. 2002. Vol. 12. No. 3. pp. 96-97.
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TY - JOUR
DO - 10.1070/MC2002v012n03ABEH001573
UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n03ABEH001573
TI - Preparation of 1,2-bis(3,4-dicyanophenoxymethyl)benzene and the binuclear zinc phthalocyanine derived from it
T2 - Mendeleev Communications
AU - Tolbin, Alexander Yurevich
AU - Ivanov, Alexey V
AU - Tomilova, Larisa Godvigovna
AU - Zefirov, Nikolai Serafimovich
PY - 2002
DA - 2002/07/05
PB - Mendeleev Communications
SP - 96-97
IS - 3
VL - 12
ER -
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@article{2002_Tolbin,
author = {Alexander Yurevich Tolbin and Alexey V Ivanov and Larisa Godvigovna Tomilova and Nikolai Serafimovich Zefirov},
title = {Preparation of 1,2-bis(3,4-dicyanophenoxymethyl)benzene and the binuclear zinc phthalocyanine derived from it},
journal = {Mendeleev Communications},
year = {2002},
volume = {12},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n03ABEH001573},
number = {3},
pages = {96--97},
doi = {10.1070/MC2002v012n03ABEH001573}
}
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Tolbin, Alexander Yurevich, et al. “Preparation of 1,2-bis(3,4-dicyanophenoxymethyl)benzene and the binuclear zinc phthalocyanine derived from it.” Mendeleev Communications, vol. 12, no. 3, Jul. 2002, pp. 96-97. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n03ABEH001573.

Abstract

A method of synthesis of 1,2-bis(3,4-dicyanophenoxymethyl)benzene from the 1,2-bis(hydroxymethyl)benzene and 4-nitrophthalodinitrile is developed. Its tetramerization with Zn(OAc)2·2H2O gives a binuclear zinc phthalocyanine of a new type, containing four o-phenylidene bridges. The use of microwave heating decreases reaction time and increases yield.

References

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