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Synthesis and structure of new triphenylphosphine π-complexes of palladium(0) with p-benzoquinone and their role in the oxidative carbonylation of alkynes

Alexander Victorovich Kulik 1
Alexander Victorovich Kulik
, 
Lev Grigor'evich Bruk 1
Lev Grigor'evich Bruk
, 
Oleg Naumovich Temkin 1
Oleg Naumovich Temkin
, 
Vil'dar Ravuilevich Khabibulin 1
Vil'dar Ravuilevich Khabibulin
, 
Vitaly Konstantinovich Belsky 2
Vitaly Konstantinovich Belsky
, 
Valery Efimovich Zavodnik 2
Valery Efimovich Zavodnik
10.1070/MC2002v012n02ABEH001577
Published 2002-04-30
Communication , Volume 12, Issue 2, 47-48
13
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Kulik A. V. et al. Synthesis and structure of new triphenylphosphine π-complexes of palladium(0) with p-benzoquinone and their role in the oxidative carbonylation of alkynes // Mendeleev Communications. 2002. Vol. 12. No. 2. pp. 47-48.
GOST all authors (up to 50) Copy
Kulik A. V., Bruk L. G., Temkin O. N., Khabibulin V. R., Belsky V. K., Zavodnik V. E. Synthesis and structure of new triphenylphosphine π-complexes of palladium(0) with p-benzoquinone and their role in the oxidative carbonylation of alkynes // Mendeleev Communications. 2002. Vol. 12. No. 2. pp. 47-48.
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TY - JOUR
DO - 10.1070/MC2002v012n02ABEH001577
UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n02ABEH001577
TI - Synthesis and structure of new triphenylphosphine π-complexes of palladium(0) with p-benzoquinone and their role in the oxidative carbonylation of alkynes
T2 - Mendeleev Communications
AU - Kulik, Alexander Victorovich
AU - Bruk, Lev Grigor'evich
AU - Temkin, Oleg Naumovich
AU - Khabibulin, Vil'dar Ravuilevich
AU - Belsky, Vitaly Konstantinovich
AU - Zavodnik, Valery Efimovich
PY - 2002
DA - 2002/04/30
PB - Mendeleev Communications
SP - 47-48
IS - 2
VL - 12
ER -
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@article{2002_Kulik,
author = {Alexander Victorovich Kulik and Lev Grigor'evich Bruk and Oleg Naumovich Temkin and Vil'dar Ravuilevich Khabibulin and Vitaly Konstantinovich Belsky and Valery Efimovich Zavodnik},
title = {Synthesis and structure of new triphenylphosphine π-complexes of palladium(0) with p-benzoquinone and their role in the oxidative carbonylation of alkynes},
journal = {Mendeleev Communications},
year = {2002},
volume = {12},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n02ABEH001577},
number = {2},
pages = {47--48},
doi = {10.1070/MC2002v012n02ABEH001577}
}
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Cite this
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Kulik, Alexander Victorovich, et al. “Synthesis and structure of new triphenylphosphine π-complexes of palladium(0) with p-benzoquinone and their role in the oxidative carbonylation of alkynes.” Mendeleev Communications, vol. 12, no. 2, Apr. 2002, pp. 47-48. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n02ABEH001577.

Abstract

The complexes Pd(η2-Q)(PPh3)22H2Q and Pd2(μ-η2,η2-Q)2(PPh3)2 (where Q and H2Q are p-benzoquinone and hydroquinone, respectively) were synthesised and structurally characterised, and their catalytic activity in the oxidative carbonylation of phenylacetylene to methyl phenylpropiolate was examined.

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