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Synthesis of functionalised bipyridines by sequential nucleophilic substitution of hydrogen and cycloaddition in 1,2,4-triazine rings

Dmitry Nikolaevich Kozhevnikov 1
Dmitry Nikolaevich Kozhevnikov
, 
Valery Nikolaevich Kozhevnikov 1
Valery Nikolaevich Kozhevnikov
, 
Tatiana Vladimirovna Nikitina 1
Tatiana Vladimirovna Nikitina
, 
Vladimir Leonidovich Rusinov 1
Vladimir Leonidovich Rusinov
, 
Oleg Nikolaevich Chupakhin 1
Oleg Nikolaevich Chupakhin
, 
Hans Neunhoeffer 2
Hans Neunhoeffer
10.1070/MC2002v012n01ABEH001548
Published 2002-03-11
Communication , Volume 12, Issue 1, 30-32
11
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Kozhevnikov D. N. et al. Synthesis of functionalised bipyridines by sequential nucleophilic substitution of hydrogen and cycloaddition in 1,2,4-triazine rings // Mendeleev Communications. 2002. Vol. 12. No. 1. pp. 30-32.
GOST all authors (up to 50) Copy
Kozhevnikov D. N., Kozhevnikov V. N., Nikitina T. V., Rusinov V. L., Chupakhin O. N., Neunhoeffer H. Synthesis of functionalised bipyridines by sequential nucleophilic substitution of hydrogen and cycloaddition in 1,2,4-triazine rings // Mendeleev Communications. 2002. Vol. 12. No. 1. pp. 30-32.
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TY - JOUR
DO - 10.1070/MC2002v012n01ABEH001548
UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001548
TI - Synthesis of functionalised bipyridines by sequential nucleophilic substitution of hydrogen and cycloaddition in 1,2,4-triazine rings
T2 - Mendeleev Communications
AU - Kozhevnikov, Dmitry Nikolaevich
AU - Kozhevnikov, Valery Nikolaevich
AU - Nikitina, Tatiana Vladimirovna
AU - Rusinov, Vladimir Leonidovich
AU - Chupakhin, Oleg Nikolaevich
AU - Neunhoeffer, Hans
PY - 2002
DA - 2002/03/11
PB - Mendeleev Communications
SP - 30-32
IS - 1
VL - 12
ER -
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@article{2002_Kozhevnikov,
author = {Dmitry Nikolaevich Kozhevnikov and Valery Nikolaevich Kozhevnikov and Tatiana Vladimirovna Nikitina and Vladimir Leonidovich Rusinov and Oleg Nikolaevich Chupakhin and Hans Neunhoeffer},
title = {Synthesis of functionalised bipyridines by sequential nucleophilic substitution of hydrogen and cycloaddition in 1,2,4-triazine rings},
journal = {Mendeleev Communications},
year = {2002},
volume = {12},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001548},
number = {1},
pages = {30--32},
doi = {10.1070/MC2002v012n01ABEH001548}
}
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Kozhevnikov, Dmitry Nikolaevich, et al. “Synthesis of functionalised bipyridines by sequential nucleophilic substitution of hydrogen and cycloaddition in 1,2,4-triazine rings.” Mendeleev Communications, vol. 12, no. 1, Mar. 2002, pp. 30-32. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001548.

Abstract

A new methodology for the synthesis of functionalised bipyridines by the direct cyanation of 3-(2-pyridyl)-1,2,4-triazine 4-oxide through nucleophilic substitution for hydrogen followed by the transformation of the 1,2,4-triazine ring into the pyridine ring by the Diels–Alder reaction and, finally, the chemical conversion of the cyano group is described.

References

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10.1070/MC2002v012n01ABEH001548_bib1
Lehn
Supramolecular Chemistry – Concepts and Perspectives, 1995
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Self-Assembling Supramolecular Complexes
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Chemical Reviews, 1995
3.
Kozhevnikov D.N., Kozhevnikov V.N., Rusinov V.L., Chupakhin O.N.
Mendeleev Communications, 1997