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A cobalt(II)—porphyrin complex as a regulator of cross-linking radical copolymerization

, 
Evgenia Olegovna Perepelitsina 1
Evgenia Olegovna Perepelitsina
, 
Maria L Bubnova 1
Maria L Bubnova
, 
Genrietta Alekseevna Estrina 1
Genrietta Alekseevna Estrina
, 
Valentin Petrovich Roshchupkin 1
Valentin Petrovich Roshchupkin
10.1070/MC2002v012n01ABEH001544
Published 2002-03-11
Communication , Volume 12, Issue 1, 21-23
7
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Kurmaz S. V. et al. A cobalt(II)—porphyrin complex as a regulator of cross-linking radical copolymerization // Mendeleev Communications. 2002. Vol. 12. No. 1. pp. 21-23.
GOST all authors (up to 50) Copy
Kurmaz S. V., Perepelitsina E. O., Bubnova M. L., Estrina G. A., Roshchupkin V. P. A cobalt(II)—porphyrin complex as a regulator of cross-linking radical copolymerization // Mendeleev Communications. 2002. Vol. 12. No. 1. pp. 21-23.
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TY - JOUR
DO - 10.1070/MC2002v012n01ABEH001544
UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001544
TI - A cobalt(II)—porphyrin complex as a regulator of cross-linking radical copolymerization
T2 - Mendeleev Communications
AU - Kurmaz, Svetlana Viktorovna
AU - Perepelitsina, Evgenia Olegovna
AU - Bubnova, Maria L
AU - Estrina, Genrietta Alekseevna
AU - Roshchupkin, Valentin Petrovich
PY - 2002
DA - 2002/03/11
PB - Mendeleev Communications
SP - 21-23
IS - 1
VL - 12
ER -
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@article{2002_Kurmaz,
author = {Svetlana Viktorovna Kurmaz and Evgenia Olegovna Perepelitsina and Maria L Bubnova and Genrietta Alekseevna Estrina and Valentin Petrovich Roshchupkin},
title = {A cobalt(II)—porphyrin complex as a regulator of cross-linking radical copolymerization},
journal = {Mendeleev Communications},
year = {2002},
volume = {12},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001544},
number = {1},
pages = {21--23},
doi = {10.1070/MC2002v012n01ABEH001544}
}
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Kurmaz, Svetlana Viktorovna, et al. “A cobalt(II)—porphyrin complex as a regulator of cross-linking radical copolymerization.” Mendeleev Communications, vol. 12, no. 1, Mar. 2002, pp. 21-23. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001544.

Abstract

The additions of a porphyrin cobalt complex diminished the rate of cross-linking copolymerization of ethylene glycol dimethacrylate (EGDMA) and styrene, shifted the autoacceleration process towards higher degrees of monomer conversions and modified the structure and properties of resulting cross-linked copolymers owing to catalytic chain transfer reaction, catalytic inhibition reaction and chain regeneration as a result of the reversible breakdown of a Co–C bond.

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