Home / Publications / Dichlorosilane chlorination in the presence of propylene as an inhibitor at low pressures and 293 K

Dichlorosilane chlorination in the presence of propylene as an inhibitor at low pressures and 293 K

Nikolai Mihailovich Rubtsov 1
Nikolai Mihailovich Rubtsov
, 
Georgii Igorevich Tsvetkov 1
Georgii Igorevich Tsvetkov
, 
Victor Iosifovich Chernysh 1
Victor Iosifovich Chernysh
10.1070/MC2002v012n01ABEH001537
Published 2002-03-11
Communication , Volume 12, Issue 1, 37-39
1
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Rubtsov N. M., Tsvetkov G. I., Chernysh V. I. Dichlorosilane chlorination in the presence of propylene as an inhibitor at low pressures and 293 K // Mendeleev Communications. 2002. Vol. 12. No. 1. pp. 37-39.
GOST all authors (up to 50) Copy
Rubtsov N. M., Tsvetkov G. I., Chernysh V. I. Dichlorosilane chlorination in the presence of propylene as an inhibitor at low pressures and 293 K // Mendeleev Communications. 2002. Vol. 12. No. 1. pp. 37-39.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2002v012n01ABEH001537
UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001537
TI - Dichlorosilane chlorination in the presence of propylene as an inhibitor at low pressures and 293 K
T2 - Mendeleev Communications
AU - Rubtsov, Nikolai Mihailovich
AU - Tsvetkov, Georgii Igorevich
AU - Chernysh, Victor Iosifovich
PY - 2002
DA - 2002/03/11
PB - Mendeleev Communications
SP - 37-39
IS - 1
VL - 12
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2002_Rubtsov,
author = {Nikolai Mihailovich Rubtsov and Georgii Igorevich Tsvetkov and Victor Iosifovich Chernysh},
title = {Dichlorosilane chlorination in the presence of propylene as an inhibitor at low pressures and 293 K},
journal = {Mendeleev Communications},
year = {2002},
volume = {12},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001537},
number = {1},
pages = {37--39},
doi = {10.1070/MC2002v012n01ABEH001537}
}
MLA
Cite this
MLA Copy
Rubtsov, Nikolai Mihailovich, et al. “Dichlorosilane chlorination in the presence of propylene as an inhibitor at low pressures and 293 K.” Mendeleev Communications, vol. 12, no. 1, Mar. 2002, pp. 37-39. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001537.

Abstract

The strong inhibiting effect of C3H6 on the self-ignition of dichlorosilane–chlorine mixtures points to silylenes as chain carriers of the reaction. A critical concentration of chemically inert SF6 (> 45%) drastically improves the inhibiting action of C3H6 indicating the occurrence of energy branching.

References

1.
10.1070/MC2002v012n01ABEH001537_bib1
Chesnokov
Dokl. Akad. Nauk SSSR, 1981
2.
10.1070/MC2002v012n01ABEH001537_bib2
Rubtsov
Kinet.Katal., 1997
3.
10.1070/MC2002v012n01ABEH001537_bib3
Azatyan
Khim. Fiz., 1983
4.
10.1070/MC2002v012n01ABEH001537_bib4
Aivazyan
Khim. Fiz., 1997
5.
10.1070/MC2002v012n01ABEH001537_bib5
Begishev
Zh. Fiz. Khim., 1994
6.
10.1070/MC2002v012n01ABEH001537_bib6
Azatyan
Kinet. Katal., 1988
7.
10.1070/MC2002v012n01ABEH001537_bib7
Azatyan
Izv. Akad. Nauk SSSR, Ser. Khim., 1976
8.
N. N. Semenov, O, Akad. Nauk SSSR, Moscow, 1958, p. 685 (in Russian).
9.
10.1070/MC2002v012n01ABEH001537_bib9
Denisov
Ingibirovanie tsepnykh reaktsii (Inhibition of Chain Reactions), 1997
10.
10.1070/MC2002v012n01ABEH001537_bib10
Azatyan
Fiz. Gorenia Vzryva, 1980
11.
V. I. Vedeneev and A. E. Shilov, in Fizicheskaya khimiya, Sovremennyeproblemy (Physical Chemistry, Contemporary Problems), Khimiya,Moscow, 1985, p. 7 (in Russian).
13.
Rate constants for silylene reactions
Safarik I., Sandhu V., Lown E.M., Strausz O.P., Bell T.N.
Research on Chemical Intermediates, 1990
14.
10.1070/MC2002v012n01ABEH001537_bib14
Parijskaya
Kinet. Katal., 1973
15.
10.1070/MC2002v012n01ABEH001537_bib15
Rubtsov
Izv. Akad. NaukSSSR, Ser. Khim., 1980
16.
10.1070/MC2002v012n01ABEH001537_bib16
Azatyan
Kinet. Katal., 1975
17.
Reactions of silanes with halogens: chemiluminescent products in the ultraviolet-visible spectrum
Conner C.P., Stewart G.W., Lindsay D.M., Gole J.L.
Journal of the American Chemical Society, 1977
18.
X̃A1, ã3B1, and Ã1B1 States of SiCl2:  Ab Initio Calculations and Simulation of Emission Spectra
Chau F., Wang D., Lee E.P., Dyke J.M., Mok D.K.
Journal of Physical Chemistry A, 1999
19.
10.1070/MC2002v012n01ABEH001537_bib19
Azatyan
Kinet. Katal., 1999
20.
L. V. Gurvich, G. V. Karachentsev and V. N. Kondratiev, Energii razryva khimicheskikh svyazei. Potentsialy ionizatsii (Chemical Bonds Energies. Ionization Potentials), Nauka, Moscow, 1976 (in Russian).