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Difluorination ability of F-TEDA-BF4 in the transannular cyclization of bicyclo[3.3.1]nonane dienes in monoglyme

Yurii Alekseevich Serguchev 1
Yurii Alekseevich Serguchev
, 
Lyudmila Fedorovna Lourie 1
Lyudmila Fedorovna Lourie
, 
Maksim Vladimirovich Ponomarenko 1
Maksim Vladimirovich Ponomarenko
1 Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
10.1070/MC2002v012n01ABEH001531
Published 2002-03-11
Communication , Volume 12, Issue 1, 23-25
11
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Serguchev Y. A., Lourie L. F., Ponomarenko M. V. Difluorination ability of F-TEDA-BF4 in the transannular cyclization of bicyclo[3.3.1]nonane dienes in monoglyme // Mendeleev Communications. 2002. Vol. 12. No. 1. pp. 23-25.
GOST all authors (up to 50) Copy
Serguchev Y. A., Lourie L. F., Ponomarenko M. V. Difluorination ability of F-TEDA-BF4 in the transannular cyclization of bicyclo[3.3.1]nonane dienes in monoglyme // Mendeleev Communications. 2002. Vol. 12. No. 1. pp. 23-25.
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TY - JOUR
DO - 10.1070/MC2002v012n01ABEH001531
UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001531
TI - Difluorination ability of F-TEDA-BF4 in the transannular cyclization of bicyclo[3.3.1]nonane dienes in monoglyme
T2 - Mendeleev Communications
AU - Serguchev, Yurii Alekseevich
AU - Lourie, Lyudmila Fedorovna
AU - Ponomarenko, Maksim Vladimirovich
PY - 2002
DA - 2002/03/11
PB - Mendeleev Communications
SP - 23-25
IS - 1
VL - 12
ER -
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@article{2002_Serguchev,
author = {Yurii Alekseevich Serguchev and Lyudmila Fedorovna Lourie and Maksim Vladimirovich Ponomarenko},
title = {Difluorination ability of F-TEDA-BF4 in the transannular cyclization of bicyclo[3.3.1]nonane dienes in monoglyme},
journal = {Mendeleev Communications},
year = {2002},
volume = {12},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001531},
number = {1},
pages = {23--25},
doi = {10.1070/MC2002v012n01ABEH001531}
}
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Serguchev, Yurii Alekseevich, et al. “Difluorination ability of F-TEDA-BF4 in the transannular cyclization of bicyclo[3.3.1]nonane dienes in monoglyme.” Mendeleev Communications, vol. 12, no. 1, Mar. 2002, pp. 23-25. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001531.

Abstract

The interaction of 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) (F-TEDA-BF4) with 3,7-bismethylenebicyclo[3.3.1]nonane and its derivatives in monoglyme results in the transannular cyclization of the dienes to form 1-fluoro-3-fluoroalkyladamantanes.

References

1.
Electrophilic NF Fluorinating Agents
Lal G.S., Pez G.P., Syvret R.G.
Chemical Reviews, 1996
5.
10.1070/MC2002v012n01ABEH001531_bib5
Krasutskii
Zh. Org. Khim., 1985
6.
10.1070/MC2002v012n01ABEH001531_bib6
Tishchenko
Teor. Eksp. Khim., 2000
7.
NO2+-containing reagents in the electrophilic and oxidative addition to propellanic C-C bond
Fokin A.A., Gunchenko P.A., Kulik N.I., Iksanova S.V., Krasutsky P.A., Gogoman I.V., Yurchenko A.G.
Tetrahedron, 1996