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Synthesis and reactivity of extremely thermally stable trialkylpalladium(IV) complexes supported with 1,4,7-triazacyclononane

Anton Aleksandrovich Sobanov ¹

Anton Aleksandrovich Sobanov

Andrei Nikolaevich Vedernikov ¹

Andrei Nikolaevich Vedernikov

Gerald Dyker ²

Gerald Dyker

Boris Nikolaevich Solomonov ¹

Boris Nikolaevich Solomonov

¹ Department of Chemistry, V.I. Ul'yanov-Lenin Kazan State University, Kazan, Russian Federation

² Gerhard-Mercator-Universitaet Duisburg, FB 6 - Institut fuer Synthesechemie, Duisburg, Germany

10.1070/MC2002v012n01ABEH001530

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Published 2002-03-11

Communication , Volume 12, Issue 1, 14-15

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Sobanov A. A. et al. Synthesis and reactivity of extremely thermally stable trialkylpalladium(IV) complexes supported with 1,4,7-triazacyclononane // Mendeleev Communications. 2002. Vol. 12. No. 1. pp. 14-15.

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Sobanov A. A., Vedernikov A. N., Dyker G., Solomonov B. N. Synthesis and reactivity of extremely thermally stable trialkylpalladium(IV) complexes supported with 1,4,7-triazacyclononane // Mendeleev Communications. 2002. Vol. 12. No. 1. pp. 14-15.

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TY - JOUR

DO - 10.1070/MC2002v012n01ABEH001530

UR - https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001530

TI - Synthesis and reactivity of extremely thermally stable trialkylpalladium(IV) complexes supported with 1,4,7-triazacyclononane

T2 - Mendeleev Communications

AU - Sobanov, Anton Aleksandrovich

AU - Vedernikov, Andrei Nikolaevich

AU - Dyker, Gerald

AU - Solomonov, Boris Nikolaevich

PY - 2002

DA - 2002/03/11

PB - Mendeleev Communications

SP - 14-15

IS - 1

VL - 12

ER -

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@article{2002_Sobanov,

author = {Anton Aleksandrovich Sobanov and Andrei Nikolaevich Vedernikov and Gerald Dyker and Boris Nikolaevich Solomonov},

title = {Synthesis and reactivity of extremely thermally stable trialkylpalladium(IV) complexes supported with 1,4,7-triazacyclononane},

journal = {Mendeleev Communications},

year = {2002},

volume = {12},

publisher = {Mendeleev Communications},

month = {Mar},

url = {https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001530},

number = {1},

pages = {14--15},

doi = {10.1070/MC2002v012n01ABEH001530}

}

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Sobanov, Anton Aleksandrovich, et al. “Synthesis and reactivity of extremely thermally stable trialkylpalladium(IV) complexes supported with 1,4,7-triazacyclononane.” Mendeleev Communications, vol. 12, no. 1, Mar. 2002, pp. 14-15. https://mendcomm.colab.ws/publications/10.1070/MC2002v012n01ABEH001530.

Abstract

The dimethylpalladium(II) PdMe₂(tacn) complex supported with 1,4,7-triazacyclononane (tacn), obtained in situ via a reaction etween PdMe₂(tmeda) and tacn reacts with methyl or ethyl iodide (RI) to form the most stable trialkyl palladium(IV) complexes [PdMe₂R(tacn)]I.

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