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Synthesis of the first representatives of 3-ethynyldiaziridines

Nina Nikolaevna Makhova 1
Nina Nikolaevna Makhova
, 
Nailya G Kamalova 1
Nailya G Kamalova
, 
Yurii Andreevich Strelenko 1
Yurii Andreevich Strelenko
10.1070/MC2001v011n06ABEH001500
Published 2001-12-18
Communication , Volume 11, Issue 6, 227-229
3
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Makhova N. N., Kamalova N. G., Strelenko Y. A. Synthesis of the first representatives of 3-ethynyldiaziridines // Mendeleev Communications. 2001. Vol. 11. No. 6. pp. 227-229.
GOST all authors (up to 50) Copy
Makhova N. N., Kamalova N. G., Strelenko Y. A. Synthesis of the first representatives of 3-ethynyldiaziridines // Mendeleev Communications. 2001. Vol. 11. No. 6. pp. 227-229.
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TY - JOUR
DO - 10.1070/MC2001v011n06ABEH001500
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n06ABEH001500
TI - Synthesis of the first representatives of 3-ethynyldiaziridines
T2 - Mendeleev Communications
AU - Makhova, Nina Nikolaevna
AU - Kamalova, Nailya G
AU - Strelenko, Yurii Andreevich
PY - 2001
DA - 2001/12/18
PB - Mendeleev Communications
SP - 227-229
IS - 6
VL - 11
ER -
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@article{2001_Makhova,
author = {Nina Nikolaevna Makhova and Nailya G Kamalova and Yurii Andreevich Strelenko},
title = {Synthesis of the first representatives of 3-ethynyldiaziridines},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n06ABEH001500},
number = {6},
pages = {227--229},
doi = {10.1070/MC2001v011n06ABEH001500}
}
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Makhova, Nina Nikolaevna, et al. “Synthesis of the first representatives of 3-ethynyldiaziridines.” Mendeleev Communications, vol. 11, no. 6, Dec. 2001, pp. 227-229. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n06ABEH001500.

Abstract

1,2-Dimethyl-3-(3,3-diethoxypropyn-1-yl)-and 1,2-dimethyl-3-(3-hydroxymethyl-3-methylbutyn-1-yl)diaziridines have been synthesised by the interaction of 4,4-diethoxybutyn-2-al and 4-hydroxymethyl-4-methylpentyn-2-al, respectively, with equimolar amounts of MeNH2 and MeNHCl (or MeNHOSO3H) at pH 9.5–10; the use of an excess of an amine in reactions with 4,4-diethoxybutyn-2-al resulted in a mixture of isomeric 5(3)-diethoxymethyl-1-methylpyrazoles and a mixture of Z/E isomers of 1-cyano- 3,3-diethoxy-2-methylaminoprop-1-enes.

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