Home / Publications / Octacoordinated main-group element centres in a planar cyclic B8 environment: an ab initio study

Octacoordinated main-group element centres in a planar cyclic B8 environment: an ab initio study

Ruslan Mikhailovich Minyaev 1
Ruslan Mikhailovich Minyaev
, 
Tatyana N Gribanova 1
Tatyana N Gribanova
, 
Andrey Georgievich Starikov 1
Andrey Georgievich Starikov
, 
Vladimir Isaakovich Minkin 1
Vladimir Isaakovich Minkin
10.1070/MC2001v011n06ABEH001496
Published 2001-12-18
Communication , Volume 11, Issue 6, 213-214
63
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Minyaev R. M. et al. Octacoordinated main-group element centres in a planar cyclic B8 environment: an ab initio study // Mendeleev Communications. 2001. Vol. 11. No. 6. pp. 213-214.
GOST all authors (up to 50) Copy
Minyaev R. M., Gribanova T. N., Starikov A. G., Minkin V. I. Octacoordinated main-group element centres in a planar cyclic B8 environment: an ab initio study // Mendeleev Communications. 2001. Vol. 11. No. 6. pp. 213-214.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2001v011n06ABEH001496
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n06ABEH001496
TI - Octacoordinated main-group element centres in a planar cyclic B8 environment: an ab initio study
T2 - Mendeleev Communications
AU - Minyaev, Ruslan Mikhailovich
AU - Gribanova, Tatyana N
AU - Starikov, Andrey Georgievich
AU - Minkin, Vladimir Isaakovich
PY - 2001
DA - 2001/12/18
PB - Mendeleev Communications
SP - 213-214
IS - 6
VL - 11
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2001_Minyaev,
author = {Ruslan Mikhailovich Minyaev and Tatyana N Gribanova and Andrey Georgievich Starikov and Vladimir Isaakovich Minkin},
title = {Octacoordinated main-group element centres in a planar cyclic B8 environment: an ab initio study},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n06ABEH001496},
number = {6},
pages = {213--214},
doi = {10.1070/MC2001v011n06ABEH001496}
}
MLA
Cite this
MLA Copy
Minyaev, Ruslan Mikhailovich, et al. “Octacoordinated main-group element centres in a planar cyclic B8 environment: an ab initio study.” Mendeleev Communications, vol. 11, no. 6, Dec. 2001, pp. 213-214. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n06ABEH001496.

Abstract

Density functional theory [B3LYP/6-311G(2df)] calculations predict stable planar structures of the nonclassical compounds XB8 (X = Si, P+) containing central octacoordinated silicon and phosphorus atoms, and a fluxional structure of CB8 with effective octacoordination of the carbon atom.

References

1.
10.1070/MC2001v011n06ABEH001496_bib1
Minkin
Nonclassical Structures of Organic Compounds, 1987
2.
10.1070/MC2001v011n06ABEH001496_bib2
Minyaev
Izv. Akad. Nauk, Ser. Khim., 2000
3.
Observation of all-metal aromatic molecules.
Li X., Kuznetsov A.E., Zhang H., Boldyrev A.I., Wang L.
Science, 2001
5.
Planar tetracoordinate carbon
Hoffmann R., Alder R.W., Wilcox C.F.
Journal of the American Chemical Society, 1970
6.
Planar and inherently non-tetrahedral tetracoordinate carbon: a status report *
Sorger K., Ragué^Schleyer P.V.
Journal of Molecular Structure THEOCHEM, 1995
7.
Gribanova T.N., Minyaev R.M., Minkin V.I.
Collection of Czechoslovak Chemical Communications, 2002
8.
Gribanova T.N., Minyaev R.M., Minkin V.I.
Mendeleev Communications, 2001
9.
10.1070/MC2001v011n06ABEH001496_bib9
Frisch
Gaussian 98, Revision A.9, 1998
10.
10.1070/MC2001v011n06ABEH001496_bib10
Hargittai
The Molecular Geometries of Coordination Compounds in Vapour Phase, 1975