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Xenon difluoride–trimethylsilyl isocyanate–triflic acid as a new system for the amination of aromatic compounds

Namig Sharafeddin ogly Pirkuliev 1
Namig Sharafeddin ogly Pirkuliev
,  , 
Novruz Guseingulu ogly Akhmedov 2
Novruz Guseingulu ogly Akhmedov
, 
Nikolai Serafimovich Zefirov 2
Nikolai Serafimovich Zefirov
, 
Peter J Stang 3
Peter J Stang
10.1070/MC2001v011n05ABEH001514
Published 2001-10-23
Communication , Volume 11, Issue 5, 172-173
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Pirkuliev N. S. O. et al. Xenon difluoride–trimethylsilyl isocyanate–triflic acid as a new system for the amination of aromatic compounds // Mendeleev Communications. 2001. Vol. 11. No. 5. pp. 172-173.
GOST all authors (up to 50) Copy
Pirkuliev N. S. O., Brel V. K., Akhmedov N. G. O., Zefirov N. S., Stang P. J. Xenon difluoride–trimethylsilyl isocyanate–triflic acid as a new system for the amination of aromatic compounds // Mendeleev Communications. 2001. Vol. 11. No. 5. pp. 172-173.
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TY - JOUR
DO - 10.1070/MC2001v011n05ABEH001514
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n05ABEH001514
TI - Xenon difluoride–trimethylsilyl isocyanate–triflic acid as a new system for the amination of aromatic compounds
T2 - Mendeleev Communications
AU - Pirkuliev, Namig Sharafeddin ogly
AU - Brel, Valery Kuzmich
AU - Akhmedov, Novruz Guseingulu ogly
AU - Zefirov, Nikolai Serafimovich
AU - Stang, Peter J
PY - 2001
DA - 2001/10/23
PB - Mendeleev Communications
SP - 172-173
IS - 5
VL - 11
ER -
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@article{2001_Pirkuliev,
author = {Namig Sharafeddin ogly Pirkuliev and Valery Kuzmich Brel and Novruz Guseingulu ogly Akhmedov and Nikolai Serafimovich Zefirov and Peter J Stang},
title = {Xenon difluoride–trimethylsilyl isocyanate–triflic acid as a new system for the amination of aromatic compounds},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n05ABEH001514},
number = {5},
pages = {172--173},
doi = {10.1070/MC2001v011n05ABEH001514}
}
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Cite this
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Pirkuliev, Namig Sharafeddin ogly, et al. “Xenon difluoride–trimethylsilyl isocyanate–triflic acid as a new system for the amination of aromatic compounds.” Mendeleev Communications, vol. 11, no. 5, Oct. 2001, pp. 172-173. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n05ABEH001514.

Abstract

In the title system, OCNXeOSO2CF3 is formed, which readily oxidises iodobenzene to PhI+–NCO –OTf. The direct amination of aromatic substrates is possible with the use of XeF2–Me3SiNCO–CF3SO3H.

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