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Direct conversion of N-ethylamines into functionalised amides by S2Cl2

Lidia Sergeevna Konstantinova 1
Lidia Sergeevna Konstantinova
, 
Oleg Alexeevich Rakitin 1
Oleg Alexeevich Rakitin
, 
Charles W Rees 2
Charles W Rees
10.1070/MC2001v011n05ABEH001504
Published 2001-10-23
Communication , Volume 11, Issue 5, 167-168
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Konstantinova L. S., Rakitin O. A., Rees C. W. Direct conversion of N-ethylamines into functionalised amides by S2Cl2 // Mendeleev Communications. 2001. Vol. 11. No. 5. pp. 167-168.
GOST all authors (up to 50) Copy
Konstantinova L. S., Rakitin O. A., Rees C. W. Direct conversion of N-ethylamines into functionalised amides by S2Cl2 // Mendeleev Communications. 2001. Vol. 11. No. 5. pp. 167-168.
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TY - JOUR
DO - 10.1070/MC2001v011n05ABEH001504
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n05ABEH001504
TI - Direct conversion of N-ethylamines into functionalised amides by S2Cl2
T2 - Mendeleev Communications
AU - Konstantinova, Lidia Sergeevna
AU - Rakitin, Oleg Alexeevich
AU - Rees, Charles W
PY - 2001
DA - 2001/10/23
PB - Mendeleev Communications
SP - 167-168
IS - 5
VL - 11
ER -
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@article{2001_Konstantinova,
author = {Lidia Sergeevna Konstantinova and Oleg Alexeevich Rakitin and Charles W Rees},
title = {Direct conversion of N-ethylamines into functionalised amides by S2Cl2},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n05ABEH001504},
number = {5},
pages = {167--168},
doi = {10.1070/MC2001v011n05ABEH001504}
}
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Konstantinova, Lidia Sergeevna, et al. “Direct conversion of N-ethylamines into functionalised amides by S2Cl2.” Mendeleev Communications, vol. 11, no. 5, Oct. 2001, pp. 167-168. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n05ABEH001504.

Abstract

Hünig's base 1 is known to react extensively with S2Cl2 to give monocyclic, bicyclic and fused tricyclic 1,2-dithioles with the N-ethyl group intact, but with S2Cl2 and DABCO in chloroform at 0 °C 1 is converted into dichloroacetamide 2 by selective reaction of the N-ethyl group in a new one-pot transformation; ethyl-substituted derivatives of 1, diethylisopropylamine 17 and triethylamine react similarly though the last, less bulky, amine also gives trichloroacetamide 20.

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