Home / Publications / New evidence for the electronic nature of the strong metal-support interaction effect over a Pt/TiO2 hydrogenation catalyst

New evidence for the electronic nature of the strong metal-support interaction effect over a Pt/TiO2 hydrogenation catalyst

Aleksandr Yurevich Stakheev 1
Aleksandr Yurevich Stakheev
Natalia A Gaidai 1
Natalia A Gaidai
Natal'ya Semionovna Telegina 1
Natal'ya Semionovna Telegina
Olga P. Tkachenko 1
Olga P. Tkachenko
Khabib Minachevich Minachev 1
Khabib Minachevich Minachev
Published 2001-10-23
CommunicationVolume 11, Issue 5, 186-188
16
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Stakheev A. Y. et al. New evidence for the electronic nature of the strong metal-support interaction effect over a Pt/TiO2 hydrogenation catalyst // Mendeleev Communications. 2001. Vol. 11. No. 5. pp. 186-188.
GOST all authors (up to 50) Copy
Stakheev A. Y., Shulga Y. M., Gaidai N. A., Telegina N. S., Tkachenko O. P., Kustov L. M., Minachev K. M. New evidence for the electronic nature of the strong metal-support interaction effect over a Pt/TiO2 hydrogenation catalyst // Mendeleev Communications. 2001. Vol. 11. No. 5. pp. 186-188.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2001v011n05ABEH001446
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n05ABEH001446
TI - New evidence for the electronic nature of the strong metal-support interaction effect over a Pt/TiO2 hydrogenation catalyst
T2 - Mendeleev Communications
AU - Stakheev, Aleksandr Yurevich
AU - Shulga, Yurii Makarovich
AU - Gaidai, Natalia A
AU - Telegina, Natal'ya Semionovna
AU - Tkachenko, Olga P.
AU - Kustov, Leonid Modestovich
AU - Minachev, Khabib Minachevich
PY - 2001
DA - 2001/10/23
PB - Mendeleev Communications
SP - 186-188
IS - 5
VL - 11
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2001_Stakheev,
author = {Aleksandr Yurevich Stakheev and Yurii Makarovich Shulga and Natalia A Gaidai and Natal'ya Semionovna Telegina and Olga P. Tkachenko and Leonid Modestovich Kustov and Khabib Minachevich Minachev},
title = {New evidence for the electronic nature of the strong metal-support interaction effect over a Pt/TiO2 hydrogenation catalyst},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n05ABEH001446},
number = {5},
pages = {186--188},
doi = {10.1070/MC2001v011n05ABEH001446}
}
MLA
Cite this
MLA Copy
Stakheev, Aleksandr Yurevich, et al. “New evidence for the electronic nature of the strong metal-support interaction effect over a Pt/TiO2 hydrogenation catalyst.” Mendeleev Communications, vol. 11, no. 5, Oct. 2001, pp. 186-188. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n05ABEH001446.

Abstract

Analysis of the Pt 4f line asymmetry evidenced that the suppression of the hydrogenation activity of Pt/TiO2 in the SMSI state is caused by a decrease in the d-electron density at the Fermi level of platinum particles, while the net charge of the metal particles remains unaltered.

References

1.
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
Tauster S.J., Fung S.C., Garten R.L.
Journal of the American Chemical Society, 1978
3.
Different strong metal-support interaction effects on rhodium/titanium dioxide and platinum/titanium dioxide catalysts
Resasco D.E., Fenoglio R.J., Suarez M.P., Cechini J.O.
The Journal of Physical Chemistry, 1986
4.
X-ray PHoto-Emission Studies of Strong Metal-Support Interaction (SMSI): Metal Decoration and Electronic Effects
Fleisch T.H., Bell A.T., Regalbuto J.R., Thomson R.T., Lane G.S., Wolf E.E., Hicks R.F.
Studies in Surface Science and Catalysis, 1988
7.
Crotonaldehyde Hydrogenation on Pt/TiO2and Ni/TiO2SMSI Catalysts
8.
XPS core line asymmetries in metals
Hüfner S., Wertheim G.K., Wernick J.H.
Solid State Communications, 1975
9.
10.1070/MC2001v011n05ABEH001446_bib9
Briggs
Practical Surface Analysis by Auger and X-ray Photoelectron Spectroscopy, 1983
10.
Quantitative Chemical Analysis by ESCA
Penn D.R.
Journal of Electron Spectroscopy and Related Phenomena, 1976
11.
Quantitative analysis of XPS intensities for supported catalysts
Kerkhof F.P., Moulijn J.A.
The Journal of Physical Chemistry, 1979
12.
W Grunert, A. Yu. Stakheev, E. S. Shpiro, K. Anders, R. Feldhaus, Kh. M. Minachev and W. Haupt, Reaktor-Schubstange System zur Hermetishen Uberfuhrung von Festkorperproben in Vakuumgerate, Patent no. 289596 BRD 02.05.91, 1–11.
13.
SO2 adsorption on Pt(111): HREELS, XPS and UPS study
Sun Y.-., Sloan D., Alberas D.J., Kovar M., Sun Z.-., White J.M.
Surface Science, 1994
14.
Many-electron singularity in X-ray photoemission and X-ray line spectra from metals
Doniach S., Sunjic M.
Journal of Physics C Solid State Physics, 1970
15.
Surface electronic structure and reactivity of transition and noble metals
Ruban A., Hammer B., Stoltze P., Skriver H.L., Nørskov J.K.
Journal of Molecular Catalysis A Chemical, 1997