Home / Publications / Generation of the metallonium cations [1,2-(CH2)2C5Me3OsC5Me5]2+, [1,1’-(CH2C5Me4)2Os]2+ and [1,2-(CH2)2C5Me3Os(1’-CH2C5Me4)]3+ in the CF3SO3H–O2 system

Generation of the metallonium cations [1,2-(CH2)2C5Me3OsC5Me5]2+, [1,1’-(CH2C5Me4)2Os]2+ and [1,2-(CH2)2C5Me3Os(1’-CH2C5Me4)]3+ in the CF3SO3H–O2 system

Margarita Iosifovna Rybinskaya 1
Margarita Iosifovna Rybinskaya
, 
Alla Alekseevna Kamyshova 1
Alla Alekseevna Kamyshova
, 
Arkadii Zosimovich Kreindlin 1
Arkadii Zosimovich Kreindlin
, 
Pavel Vasil'evich Petrovskii 1
Pavel Vasil'evich Petrovskii
10.1070/MC2001v011n04ABEH001456
Published 2001-08-01
Communication , Volume 11, Issue 4, 137-138
1
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Rybinskaya M. I. et al. Generation of the metallonium cations [1,2-(CH2)2C5Me3OsC5Me5]2+, [1,1’-(CH2C5Me4)2Os]2+ and [1,2-(CH2)2C5Me3Os(1’-CH2C5Me4)]3+ in the CF3SO3H–O2 system // Mendeleev Communications. 2001. Vol. 11. No. 4. pp. 137-138.
GOST all authors (up to 50) Copy
Rybinskaya M. I., Kamyshova A. A., Kreindlin A. Z., Petrovskii P. V. Generation of the metallonium cations [1,2-(CH2)2C5Me3OsC5Me5]2+, [1,1’-(CH2C5Me4)2Os]2+ and [1,2-(CH2)2C5Me3Os(1’-CH2C5Me4)]3+ in the CF3SO3H–O2 system // Mendeleev Communications. 2001. Vol. 11. No. 4. pp. 137-138.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2001v011n04ABEH001456
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n04ABEH001456
TI - Generation of the metallonium cations [1,2-(CH2)2C5Me3OsC5Me5]2+, [1,1’-(CH2C5Me4)2Os]2+ and [1,2-(CH2)2C5Me3Os(1’-CH2C5Me4)]3+ in the CF3SO3H–O2 system
T2 - Mendeleev Communications
AU - Rybinskaya, Margarita Iosifovna
AU - Kamyshova, Alla Alekseevna
AU - Kreindlin, Arkadii Zosimovich
AU - Petrovskii, Pavel Vasil'evich
PY - 2001
DA - 2001/08/01
PB - Mendeleev Communications
SP - 137-138
IS - 4
VL - 11
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2001_Rybinskaya,
author = {Margarita Iosifovna Rybinskaya and Alla Alekseevna Kamyshova and Arkadii Zosimovich Kreindlin and Pavel Vasil'evich Petrovskii},
title = {Generation of the metallonium cations [1,2-(CH2)2C5Me3OsC5Me5]2+, [1,1’-(CH2C5Me4)2Os]2+ and [1,2-(CH2)2C5Me3Os(1’-CH2C5Me4)]3+ in the CF3SO3H–O2 system},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n04ABEH001456},
number = {4},
pages = {137--138},
doi = {10.1070/MC2001v011n04ABEH001456}
}
MLA
Cite this
MLA Copy
Rybinskaya, Margarita Iosifovna, et al. “Generation of the metallonium cations [1,2-(CH2)2C5Me3OsC5Me5]2+, [1,1’-(CH2C5Me4)2Os]2+ and [1,2-(CH2)2C5Me3Os(1’-CH2C5Me4)]3+ in the CF3SO3H–O2 system.” Mendeleev Communications, vol. 11, no. 4, Aug. 2001, pp. 137-138. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n04ABEH001456.

Abstract

The title dications and trication were generated from decamethylosmocene and [C5Me5OsC5Me4CH2]+, respectively, by the interaction with dioxygen in CF3SO3H solutions.

References

1.
10.1070/MC2001v011n04ABEH001456_bib1
Kamyshova
Izv. Akad. Nauk, Ser. Khim., 1999
2.
10.1070/MC2001v011n04ABEH001456_bib2
Kamyshova
Izv. Akad. Nauk, Ser. Khim., 2000
3.
Rybinskaya M.I., Kamyshova A.A., Kreindlin A.Z., Petrovskii P.V.
Mendeleev Communications, 2000
4.
10.1070/MC2001v011n04ABEH001456_bib4
Kreindlin
Izv. Akad. Nauk SSSR, Ser. Khim., 1987
5.
Synthesis, NMR spectra and molecular orbital calculations of ruthenium and osmium dications of the type [C5Me5MC5Me3(CH2)2]2+
Kreindlin A.Z., Fedin E.I., Petrovskii P.V., Rybinskaya M.I., Minyaev R.M., Hoffmann R.
Organometallics, 1991
7.
Bis(η-pentamethylcyclopentadienyl) complexes of molybdenum, tungsten and rhenium via metal vapour synthesis
Cloke F.G., Day J.P., Green J.C., Morley C.P., Swain A.C.
Journal of the Chemical Society Dalton Transactions, 1991