Home / Publications / Transformation of myrtenoic acid nitrile to aminophospholene oxide by the reaction with dibenzylphosphine oxide: the X-ray structure of (1S*,2R*,6R*,8R*)-5-benzyl-9,9-dimethyl-5-oxo-4-phenyl- 5-phosphatricyclo[6.1.1.0^2,6]dec-3-en-3-ylamine

Transformation of myrtenoic acid nitrile to aminophospholene oxide by the reaction with dibenzylphosphine oxide: the X-ray structure of (1S,2R,6R,8R)-5-benzyl-9,9-dimethyl-5-oxo-4-phenyl- 5-phosphatricyclo[6.1.1.0^2,6]dec-3-en-3-ylamine

Vasilii Dmitrievich Kolesnik ¹

Vasilii Dmitrievich Kolesnik

Tatyana Valeryevna Rybalova ²

Tatyana Valeryevna Rybalova

Yuriy Vasil'evich Gatilov ²

Yuriy Vasil'evich Gatilov

Alexey Vasil'evich Tkachev ²

Alexey Vasil'evich Tkachev

¹ Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation

² N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

10.1070/MC2001v011n03ABEH001449

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Published 2001-05-31

Communication , Volume 11, Issue 3, 98-99

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Kolesnik V. D. et al. Transformation of myrtenoic acid nitrile to aminophospholene oxide by the reaction with dibenzylphosphine oxide: the X-ray structure of (1S*,2R*,6R*,8R*)-5-benzyl-9,9-dimethyl-5-oxo-4-phenyl- 5-phosphatricyclo[6.1.1.02,6]dec-3-en-3-ylamine // Mendeleev Communications. 2001. Vol. 11. No. 3. pp. 98-99.

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Kolesnik V. D., Rybalova T. V., Gatilov Y. V., Tkachev A. V. Transformation of myrtenoic acid nitrile to aminophospholene oxide by the reaction with dibenzylphosphine oxide: the X-ray structure of (1S*,2R*,6R*,8R*)-5-benzyl-9,9-dimethyl-5-oxo-4-phenyl- 5-phosphatricyclo[6.1.1.02,6]dec-3-en-3-ylamine // Mendeleev Communications. 2001. Vol. 11. No. 3. pp. 98-99.

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TY - JOUR

DO - 10.1070/MC2001v011n03ABEH001449

UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001449

TI - Transformation of myrtenoic acid nitrile to aminophospholene oxide by the reaction with dibenzylphosphine oxide: the X-ray structure of (1S*,2R*,6R*,8R*)-5-benzyl-9,9-dimethyl-5-oxo-4-phenyl- 5-phosphatricyclo[6.1.1.02,6]dec-3-en-3-ylamine

T2 - Mendeleev Communications

AU - Kolesnik, Vasilii Dmitrievich

AU - Rybalova, Tatyana Valeryevna

AU - Gatilov, Yuriy Vasil'evich

AU - Tkachev, Alexey Vasil'evich

PY - 2001

DA - 2001/05/31

PB - Mendeleev Communications

SP - 98-99

IS - 3

VL - 11

ER -

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@article{2001_Kolesnik,

author = {Vasilii Dmitrievich Kolesnik and Tatyana Valeryevna Rybalova and Yuriy Vasil'evich Gatilov and Alexey Vasil'evich Tkachev},

title = {Transformation of myrtenoic acid nitrile to aminophospholene oxide by the reaction with dibenzylphosphine oxide: the X-ray structure of (1S*,2R*,6R*,8R*)-5-benzyl-9,9-dimethyl-5-oxo-4-phenyl- 5-phosphatricyclo[6.1.1.02,6]dec-3-en-3-ylamine},

journal = {Mendeleev Communications},

year = {2001},

volume = {11},

publisher = {Mendeleev Communications},

month = {May},

url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001449},

number = {3},

pages = {98--99},

doi = {10.1070/MC2001v011n03ABEH001449}

}

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Kolesnik, Vasilii Dmitrievich, et al. “Transformation of myrtenoic acid nitrile to aminophospholene oxide by the reaction with dibenzylphosphine oxide: the X-ray structure of (1S*,2R*,6R*,8R*)-5-benzyl-9,9-dimethyl-5-oxo-4-phenyl- 5-phosphatricyclo[6.1.1.02,6]dec-3-en-3-ylamine.” Mendeleev Communications, vol. 11, no. 3, May. 2001, pp. 98-99. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001449.

Abstract

The reaction of dibenzylphosphine oxide with myrtenoic acid nitrile in tert-butyl methyl ether in the presence of sodium hydride results in the formation of substituted aminophospholene oxide in good yield (83%).