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A new nitrene to carbene rearrangement upon photolysis of 4-amino-2,6-diazido-3,6-dichloropyridine

Sergei Viktorovich Chapyshev 1
Sergei Viktorovich Chapyshev
, 
Paul R Serwinski 2
Paul R Serwinski
10.1070/MC2001v011n03ABEH001439
Published 2001-05-31
Communication , Volume 11, Issue 3, 92-94
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Chapyshev S. V., Serwinski P. R. A new nitrene to carbene rearrangement upon photolysis of 4-amino-2,6-diazido-3,6-dichloropyridine // Mendeleev Communications. 2001. Vol. 11. No. 3. pp. 92-94.
GOST all authors (up to 50) Copy
Chapyshev S. V., Serwinski P. R. A new nitrene to carbene rearrangement upon photolysis of 4-amino-2,6-diazido-3,6-dichloropyridine // Mendeleev Communications. 2001. Vol. 11. No. 3. pp. 92-94.
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TY - JOUR
DO - 10.1070/MC2001v011n03ABEH001439
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001439
TI - A new nitrene to carbene rearrangement upon photolysis of 4-amino-2,6-diazido-3,6-dichloropyridine
T2 - Mendeleev Communications
AU - Chapyshev, Sergei Viktorovich
AU - Serwinski, Paul R
PY - 2001
DA - 2001/05/31
PB - Mendeleev Communications
SP - 92-94
IS - 3
VL - 11
ER -
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@article{2001_Chapyshev,
author = {Sergei Viktorovich Chapyshev and Paul R Serwinski},
title = {A new nitrene to carbene rearrangement upon photolysis of 4-amino-2,6-diazido-3,6-dichloropyridine},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001439},
number = {3},
pages = {92--94},
doi = {10.1070/MC2001v011n03ABEH001439}
}
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Chapyshev, Sergei Viktorovich, and Paul R Serwinski. “A new nitrene to carbene rearrangement upon photolysis of 4-amino-2,6-diazido-3,6-dichloropyridine.” Mendeleev Communications, vol. 11, no. 3, May. 2001, pp. 92-94. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001439.

Abstract

A novel rearrangement of quintet 2,6-dinitrenopyridine to 3-nitreno-1,2-diazacycloheptatrienylidene was discovered by EPR spectroscopy during the photolysis of 4-amino-2,6-diazido-3,5-dichloropyridine in a cryogenic matrix at 77 K.

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