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Kinetic and thermodynamic control in the synthesis of methylglyoxal thioacetals from 2-ethoxypropenal

Nataliya Afanas'evna Keiko 1
Nataliya Afanas'evna Keiko
, 
Evgeniya Aleksandrovna Funtikova 1
Evgeniya Aleksandrovna Funtikova
, 
L G Stepanova 1
L G Stepanova
, 
Yuri Aleksandrovich Chuvashev 1
Yuri Aleksandrovich Chuvashev
, 
Lyudmila Ivanovna Larina 1
Lyudmila Ivanovna Larina
, 
Mikhail Grigor'evich Voronkov 1
Mikhail Grigor'evich Voronkov
10.1070/MC2001v011n03ABEH001415
Published 2001-05-31
Communication , Volume 11, Issue 3, 110-112
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Keiko N. A. et al. Kinetic and thermodynamic control in the synthesis of methylglyoxal thioacetals from 2-ethoxypropenal // Mendeleev Communications. 2001. Vol. 11. No. 3. pp. 110-112.
GOST all authors (up to 50) Copy
Keiko N. A., Funtikova E. A., Stepanova L. G., Chuvashev Y. A., Larina L. I., Voronkov M. G. Kinetic and thermodynamic control in the synthesis of methylglyoxal thioacetals from 2-ethoxypropenal // Mendeleev Communications. 2001. Vol. 11. No. 3. pp. 110-112.
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TY - JOUR
DO - 10.1070/MC2001v011n03ABEH001415
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001415
TI - Kinetic and thermodynamic control in the synthesis of methylglyoxal thioacetals from 2-ethoxypropenal
T2 - Mendeleev Communications
AU - Keiko, Nataliya Afanas'evna
AU - Funtikova, Evgeniya Aleksandrovna
AU - Stepanova, L G
AU - Chuvashev, Yuri Aleksandrovich
AU - Larina, Lyudmila Ivanovna
AU - Voronkov, Mikhail Grigor'evich
PY - 2001
DA - 2001/05/31
PB - Mendeleev Communications
SP - 110-112
IS - 3
VL - 11
ER -
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@article{2001_Keiko,
author = {Nataliya Afanas'evna Keiko and Evgeniya Aleksandrovna Funtikova and L G Stepanova and Yuri Aleksandrovich Chuvashev and Lyudmila Ivanovna Larina and Mikhail Grigor'evich Voronkov},
title = {Kinetic and thermodynamic control in the synthesis of methylglyoxal thioacetals from 2-ethoxypropenal},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001415},
number = {3},
pages = {110--112},
doi = {10.1070/MC2001v011n03ABEH001415}
}
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Keiko, Nataliya Afanas'evna, et al. “Kinetic and thermodynamic control in the synthesis of methylglyoxal thioacetals from 2-ethoxypropenal.” Mendeleev Communications, vol. 11, no. 3, May. 2001, pp. 110-112. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001415.

Abstract

Under kinetically controlled conditions, the addition of organylthiols to 2-ethoxypropenal follows the Markovnikov rule to give 2-ethoxy-2-organylthiopropanals which spontaneously isomerize to 1-ethoxy-1-organylthiopropanones in storage or in the presence of an acid catalyst.

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