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1-Trifluoroacetyl-2-trimethylstannyl- and 1-trifluoroacetyl-2-bromoacetylenes as new dienophiles in the Diels–Alder reactions

Andrei Borisovich Koldobskii 1
Andrei Borisovich Koldobskii
Olga Sergeevna Shilova 1
Olga Sergeevna Shilova
Valery Nikolaevich Kalinin 1
Valery Nikolaevich Kalinin
Published 2001-05-31
CommunicationVolume 11, Issue 3, 99-100
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Koldobskii A. B., Shilova O. S., Kalinin V. N. 1-Trifluoroacetyl-2-trimethylstannyl- and 1-trifluoroacetyl-2-bromoacetylenes as new dienophiles in the Diels–Alder reactions // Mendeleev Communications. 2001. Vol. 11. No. 3. pp. 99-100.
GOST all authors (up to 50) Copy
Koldobskii A. B., Shilova O. S., Kalinin V. N. 1-Trifluoroacetyl-2-trimethylstannyl- and 1-trifluoroacetyl-2-bromoacetylenes as new dienophiles in the Diels–Alder reactions // Mendeleev Communications. 2001. Vol. 11. No. 3. pp. 99-100.
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TY - JOUR
DO - 10.1070/MC2001v011n03ABEH001401
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001401
TI - 1-Trifluoroacetyl-2-trimethylstannyl- and 1-trifluoroacetyl-2-bromoacetylenes as new dienophiles in the Diels–Alder reactions
T2 - Mendeleev Communications
AU - Koldobskii, Andrei Borisovich
AU - Shilova, Olga Sergeevna
AU - Kalinin, Valery Nikolaevich
PY - 2001
DA - 2001/05/31
PB - Mendeleev Communications
SP - 99-100
IS - 3
VL - 11
ER -
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@article{2001_Koldobskii,
author = {Andrei Borisovich Koldobskii and Olga Sergeevna Shilova and Valery Nikolaevich Kalinin},
title = {1-Trifluoroacetyl-2-trimethylstannyl- and 1-trifluoroacetyl-2-bromoacetylenes as new dienophiles in the Diels–Alder reactions},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001401},
number = {3},
pages = {99--100},
doi = {10.1070/MC2001v011n03ABEH001401}
}
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Koldobskii, Andrei Borisovich, et al. “1-Trifluoroacetyl-2-trimethylstannyl- and 1-trifluoroacetyl-2-bromoacetylenes as new dienophiles in the Diels–Alder reactions.” Mendeleev Communications, vol. 11, no. 3, May. 2001, pp. 99-100. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001401.

Abstract

Trifluoroacetic anhydride exotermically reacts with bis(trimethylstannyl)acetylene to form previously unknown 1-trifluoroacetyl-2-trimethylstannylacetylene, which interacts with bromine to produce 1-trifluoroacetyl-2-bromoacetylene.