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Are aroylnitrenes species with a singlet ground state?

Nina Pavlovna Gritsan 1
Nina Pavlovna Gritsan
, 
Elena Anatol'evna Pritchina 2
Elena Anatol'evna Pritchina
10.1070/MC2001v011n03ABEH001376
Published 2001-05-31
Communication , Volume 11, Issue 3, 94-96
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Gritsan N. P., Pritchina E. A. Are aroylnitrenes species with a singlet ground state? // Mendeleev Communications. 2001. Vol. 11. No. 3. pp. 94-96.
GOST all authors (up to 50) Copy
Gritsan N. P., Pritchina E. A. Are aroylnitrenes species with a singlet ground state? // Mendeleev Communications. 2001. Vol. 11. No. 3. pp. 94-96.
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TY - JOUR
DO - 10.1070/MC2001v011n03ABEH001376
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001376
TI - Are aroylnitrenes species with a singlet ground state?
T2 - Mendeleev Communications
AU - Gritsan, Nina Pavlovna
AU - Pritchina, Elena Anatol'evna
PY - 2001
DA - 2001/05/31
PB - Mendeleev Communications
SP - 94-96
IS - 3
VL - 11
ER -
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@article{2001_Gritsan,
author = {Nina Pavlovna Gritsan and Elena Anatol'evna Pritchina},
title = {Are aroylnitrenes species with a singlet ground state?},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001376},
number = {3},
pages = {94--96},
doi = {10.1070/MC2001v011n03ABEH001376}
}
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Gritsan, Nina Pavlovna, and Elena Anatol'evna Pritchina. “Are aroylnitrenes species with a singlet ground state?.” Mendeleev Communications, vol. 11, no. 3, May. 2001, pp. 94-96. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n03ABEH001376.

Abstract

The B3LYP calculations of the properties of singlet and triplet benzoylnitrenes and naphthoylnitrenes testify to the stabilization of the 1A’ state relative to the 3A” state due to the intermediacy of an NCO structure between nitrene and oxazirene in the 1A’ state.

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