Home / Publications / X-ray diffraction study of DL-1,4-dimethyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-dione: the sense of twist and folding

X-ray diffraction study of DL-1,4-dimethyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-dione: the sense of twist and folding

Igor Viktorovich Vystorop 1
Igor Viktorovich Vystorop
, 
Konstantin Alexandrovich Lyssenko 2
Konstantin Alexandrovich Lyssenko
, 
Remir Grigorevich Kostyanovsky 3
Remir Grigorevich Kostyanovsky
10.1070/MC2001v011n02ABEH001421
Published 2001-04-24
Communication , Volume 11, Issue 2, 49-50
2
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Vystorop I. V., Lyssenko K. A., Kostyanovsky R. G. X-ray diffraction study of DL-1,4-dimethyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-dione: the sense of twist and folding // Mendeleev Communications. 2001. Vol. 11. No. 2. pp. 49-50.
GOST all authors (up to 50) Copy
Vystorop I. V., Lyssenko K. A., Kostyanovsky R. G. X-ray diffraction study of DL-1,4-dimethyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-dione: the sense of twist and folding // Mendeleev Communications. 2001. Vol. 11. No. 2. pp. 49-50.
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TY - JOUR
DO - 10.1070/MC2001v011n02ABEH001421
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n02ABEH001421
TI - X-ray diffraction study of DL-1,4-dimethyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-dione: the sense of twist and folding
T2 - Mendeleev Communications
AU - Vystorop, Igor Viktorovich
AU - Lyssenko, Konstantin Alexandrovich
AU - Kostyanovsky, Remir Grigorevich
PY - 2001
DA - 2001/04/24
PB - Mendeleev Communications
SP - 49-50
IS - 2
VL - 11
ER -
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@article{2001_Vystorop,
author = {Igor Viktorovich Vystorop and Konstantin Alexandrovich Lyssenko and Remir Grigorevich Kostyanovsky},
title = {X-ray diffraction study of DL-1,4-dimethyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-dione: the sense of twist and folding},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n02ABEH001421},
number = {2},
pages = {49--50},
doi = {10.1070/MC2001v011n02ABEH001421}
}
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Vystorop, Igor Viktorovich, et al. “X-ray diffraction study of DL-1,4-dimethyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-dione: the sense of twist and folding.” Mendeleev Communications, vol. 11, no. 2, Apr. 2001, pp. 49-50. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n02ABEH001421.

Abstract

The title dilactone exists in a crystalline state (110 K) as enantiomeric synchro-(+,+)-(R,R)- and synchro-(−,−)-(S,S)-twist forms (τ0 = |1.8°|) with the retention of C2 symmetry, linked by infinite zig-zag heterochiral chains (space group C2/c) by mutual H-bonds of the CH2–H⋯O=C type.

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