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Unexpected formation of 1-vinyl-2-[2′-(6′-methylpyridyl)]pyrrole from dimethylglyoxime and acetylene in the Trofimov reaction

Alexander Mikhailovich Vasil'tsov 1
Alexander Mikhailovich Vasil'tsov
, 
Alexey B Zaitsev 1
Alexey B Zaitsev
, 
Elena Yur'evna Schmidt 1
Elena Yur'evna Schmidt
, 
Albina Ivanovna Mikhaleva 1
Albina Ivanovna Mikhaleva
, 
Andrei Valer'evich Afonin 1
Andrei Valer'evich Afonin
10.1070/MC2001v011n02ABEH001405
Published 2001-04-24
Communication , Volume 11, Issue 2, 74-75
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Vasil'tsov A. M. et al. Unexpected formation of 1-vinyl-2-[2′-(6′-methylpyridyl)]pyrrole from dimethylglyoxime and acetylene in the Trofimov reaction // Mendeleev Communications. 2001. Vol. 11. No. 2. pp. 74-75.
GOST all authors (up to 50) Copy
Vasil'tsov A. M., Zaitsev A. B., Schmidt E. Y., Mikhaleva A. I., Afonin A. V. Unexpected formation of 1-vinyl-2-[2′-(6′-methylpyridyl)]pyrrole from dimethylglyoxime and acetylene in the Trofimov reaction // Mendeleev Communications. 2001. Vol. 11. No. 2. pp. 74-75.
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TY - JOUR
DO - 10.1070/MC2001v011n02ABEH001405
UR - https://mendcomm.colab.ws/publications/10.1070/MC2001v011n02ABEH001405
TI - Unexpected formation of 1-vinyl-2-[2′-(6′-methylpyridyl)]pyrrole from dimethylglyoxime and acetylene in the Trofimov reaction
T2 - Mendeleev Communications
AU - Vasil'tsov, Alexander Mikhailovich
AU - Zaitsev, Alexey B
AU - Schmidt, Elena Yur'evna
AU - Mikhaleva, Albina Ivanovna
AU - Afonin, Andrei Valer'evich
PY - 2001
DA - 2001/04/24
PB - Mendeleev Communications
SP - 74-75
IS - 2
VL - 11
ER -
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@article{2001_Vasil'tsov,
author = {Alexander Mikhailovich Vasil'tsov and Alexey B Zaitsev and Elena Yur'evna Schmidt and Albina Ivanovna Mikhaleva and Andrei Valer'evich Afonin},
title = {Unexpected formation of 1-vinyl-2-[2′-(6′-methylpyridyl)]pyrrole from dimethylglyoxime and acetylene in the Trofimov reaction},
journal = {Mendeleev Communications},
year = {2001},
volume = {11},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2001v011n02ABEH001405},
number = {2},
pages = {74--75},
doi = {10.1070/MC2001v011n02ABEH001405}
}
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Vasil'tsov, Alexander Mikhailovich, et al. “Unexpected formation of 1-vinyl-2-[2′-(6′-methylpyridyl)]pyrrole from dimethylglyoxime and acetylene in the Trofimov reaction.” Mendeleev Communications, vol. 11, no. 2, Apr. 2001, pp. 74-75. https://mendcomm.colab.ws/publications/10.1070/MC2001v011n02ABEH001405.

Abstract

Dimethylglyoxime reacts with acetylene under pressure in the KOH–DMSO system to give 1-vinyl-2-[2′-(6′-methylpyridyl)]- pyrrole along with the expected products of the Trofimov reaction (O-vinyloxime, pyrrole and dipyrrole).

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