Home / Publications / Unusual acid-induced heterocyclisation of caryophyllene-type α-amino oximes: X-ray structure of (1S,2S,5R,8S)-1,4,4,8-tetramethyl-8-morpholin-4-yl-11-oxa-10-azatricyclo[7.2.2.02,5]tridec-9-ene

Unusual acid-induced heterocyclisation of caryophyllene-type α-amino oximes: X-ray structure of (1S,2S,5R,8S)-1,4,4,8-tetramethyl-8-morpholin-4-yl-11-oxa-10-azatricyclo[7.2.2.02,5]tridec-9-ene

Alexey Vasil'evich Tkachev 1
Alexey Vasil'evich Tkachev
, 
Alexander Mikhailovich Agafontsev 2
Alexander Mikhailovich Agafontsev
, 
Tatyana Valeryevna Rybalova 1
Tatyana Valeryevna Rybalova
, 
Yuriy Vasil'evich Gatilov 1
Yuriy Vasil'evich Gatilov
10.1070/MC2000v010n06ABEH001361
Published 2000-12-07
Communication , Volume 10, Issue 6, 211-212
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Tkachev A. V. et al. Unusual acid-induced heterocyclisation of caryophyllene-type α-amino oximes: X-ray structure of (1S,2S,5R,8S)-1,4,4,8-tetramethyl-8-morpholin-4-yl-11-oxa-10-azatricyclo[7.2.2.02,5]tridec-9-ene // Mendeleev Communications. 2000. Vol. 10. No. 6. pp. 211-212.
GOST all authors (up to 50) Copy
Tkachev A. V., Agafontsev A. M., Rybalova T. V., Gatilov Y. V. Unusual acid-induced heterocyclisation of caryophyllene-type α-amino oximes: X-ray structure of (1S,2S,5R,8S)-1,4,4,8-tetramethyl-8-morpholin-4-yl-11-oxa-10-azatricyclo[7.2.2.02,5]tridec-9-ene // Mendeleev Communications. 2000. Vol. 10. No. 6. pp. 211-212.
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TY - JOUR
DO - 10.1070/MC2000v010n06ABEH001361
UR - https://mendcomm.colab.ws/publications/10.1070/MC2000v010n06ABEH001361
TI - Unusual acid-induced heterocyclisation of caryophyllene-type α-amino oximes: X-ray structure of (1S,2S,5R,8S)-1,4,4,8-tetramethyl-8-morpholin-4-yl-11-oxa-10-azatricyclo[7.2.2.02,5]tridec-9-ene
T2 - Mendeleev Communications
AU - Tkachev, Alexey Vasil'evich
AU - Agafontsev, Alexander Mikhailovich
AU - Rybalova, Tatyana Valeryevna
AU - Gatilov, Yuriy Vasil'evich
PY - 2000
DA - 2000/12/07
PB - Mendeleev Communications
SP - 211-212
IS - 6
VL - 10
ER -
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@article{2000_Tkachev,
author = {Alexey Vasil'evich Tkachev and Alexander Mikhailovich Agafontsev and Tatyana Valeryevna Rybalova and Yuriy Vasil'evich Gatilov},
title = {Unusual acid-induced heterocyclisation of caryophyllene-type α-amino oximes: X-ray structure of (1S,2S,5R,8S)-1,4,4,8-tetramethyl-8-morpholin-4-yl-11-oxa-10-azatricyclo[7.2.2.02,5]tridec-9-ene},
journal = {Mendeleev Communications},
year = {2000},
volume = {10},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2000v010n06ABEH001361},
number = {6},
pages = {211--212},
doi = {10.1070/MC2000v010n06ABEH001361}
}
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Tkachev, Alexey Vasil'evich, et al. “Unusual acid-induced heterocyclisation of caryophyllene-type α-amino oximes: X-ray structure of (1S,2S,5R,8S)-1,4,4,8-tetramethyl-8-morpholin-4-yl-11-oxa-10-azatricyclo[7.2.2.02,5]tridec-9-ene.” Mendeleev Communications, vol. 10, no. 6, Dec. 2000, pp. 211-212. https://mendcomm.colab.ws/publications/10.1070/MC2000v010n06ABEH001361.

Abstract

The acid-catalysed cyclisation of caryophyllene-type α-amino oximes results in the formation of new bridged heterocycles with the 5,6-dihydro-4H-[1,2]oxazine moiety.

References

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10.1070/MC2000v010n06ABEH001361_bib1
Tkachev
Khim. Prir. Soedin., 1987
2.
Recent advances in the chemistry of caryophyllene
G. Collado I., R. Hanson J., J. Macías-Sánchez A.
Natural Product Reports, 1998
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10.1070/MC2000v010n06ABEH001361_bib3
Tkachev
Ross. Khim. Zh., 1998
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10.1070/MC2000v010n06ABEH001361_bib4
Allen
Chemical Design Automation News, 1993
6.
A. V. Tkachev, T. V. Rybalova and Yu. V. Gatilov, Izv. Akad. Nauk, Ser. Khim., in press.