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Molecular structure of 1-methoxymethylaziridine and methoxymethyldimethylamine and anomeric effects

Igor Fedorovich Shishkov 1
Igor Fedorovich Shishkov
, 
Lyudmila Viktorovna Khristenko 1
Lyudmila Viktorovna Khristenko
, 
Lev Vasilevich Vilkov 1
Lev Vasilevich Vilkov
, 
Marwan Dakkouri 2
Marwan Dakkouri
, 
Gulnara Konstantinovna Kadorkina 3
Gulnara Konstantinovna Kadorkina
, 
Pavel Evgenievich Dormov 3
Pavel Evgenievich Dormov
, 
Remir Grigorevich Kostyanovsky 3
Remir Grigorevich Kostyanovsky
10.1070/MC2000v010n06ABEH001359
Published 2000-12-07
Communication , Volume 10, Issue 6, 217-220
3
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Shishkov I. F. et al. Molecular structure of 1-methoxymethylaziridine and methoxymethyldimethylamine and anomeric effects // Mendeleev Communications. 2000. Vol. 10. No. 6. pp. 217-220.
GOST all authors (up to 50) Copy
Shishkov I. F., Khristenko L. V., Vilkov L. V., Dakkouri M., Kadorkina G. K., Dormov P. E., Kostyanovsky R. G. Molecular structure of 1-methoxymethylaziridine and methoxymethyldimethylamine and anomeric effects // Mendeleev Communications. 2000. Vol. 10. No. 6. pp. 217-220.
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TY - JOUR
DO - 10.1070/MC2000v010n06ABEH001359
UR - https://mendcomm.colab.ws/publications/10.1070/MC2000v010n06ABEH001359
TI - Molecular structure of 1-methoxymethylaziridine and methoxymethyldimethylamine and anomeric effects
T2 - Mendeleev Communications
AU - Shishkov, Igor Fedorovich
AU - Khristenko, Lyudmila Viktorovna
AU - Vilkov, Lev Vasilevich
AU - Dakkouri, Marwan
AU - Kadorkina, Gulnara Konstantinovna
AU - Dormov, Pavel Evgenievich
AU - Kostyanovsky, Remir Grigorevich
PY - 2000
DA - 2000/12/07
PB - Mendeleev Communications
SP - 217-220
IS - 6
VL - 10
ER -
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@article{2000_Shishkov,
author = {Igor Fedorovich Shishkov and Lyudmila Viktorovna Khristenko and Lev Vasilevich Vilkov and Marwan Dakkouri and Gulnara Konstantinovna Kadorkina and Pavel Evgenievich Dormov and Remir Grigorevich Kostyanovsky},
title = {Molecular structure of 1-methoxymethylaziridine and methoxymethyldimethylamine and anomeric effects},
journal = {Mendeleev Communications},
year = {2000},
volume = {10},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2000v010n06ABEH001359},
number = {6},
pages = {217--220},
doi = {10.1070/MC2000v010n06ABEH001359}
}
MLA
Cite this
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Shishkov, Igor Fedorovich, et al. “Molecular structure of 1-methoxymethylaziridine and methoxymethyldimethylamine and anomeric effects.” Mendeleev Communications, vol. 10, no. 6, Dec. 2000, pp. 217-220. https://mendcomm.colab.ws/publications/10.1070/MC2000v010n06ABEH001359.

Abstract

For 1-methoxymethylaziridine 1 it is proved experimentally (GED) and theoretically that the equilibrium conformers are stabilized by the anomeric effects n(N) → σ*(C–O) and n(O) → σ*(C–N), whereas in the case of methoxymethyldimethylamine 2 the calculations predict the existence of a conformer appropriate to the n(N) → σ*(C–O) effect.

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