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The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions

Lucia Yarullovna Zakharova 1
Lucia Yarullovna Zakharova
, 
Farida Garafeevna Valeeva 1
Farida Garafeevna Valeeva
, 
Lyudmila Andreevna Kudryavtseva 1
Lyudmila Andreevna Kudryavtseva
, 
Aleksandr Ivanovich Konovalov 2
Aleksandr Ivanovich Konovalov
10.1070/MC2000v010n06ABEH001337
Published 2000-12-07
Communication , Volume 10, Issue 6, 241-243
3
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Zakharova L. Y. et al. The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions // Mendeleev Communications. 2000. Vol. 10. No. 6. pp. 241-243.
GOST all authors (up to 50) Copy
Zakharova L. Y., Valeeva F. G., Kudryavtseva L. A., Konovalov A. I. The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions // Mendeleev Communications. 2000. Vol. 10. No. 6. pp. 241-243.
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TY - JOUR
DO - 10.1070/MC2000v010n06ABEH001337
UR - https://mendcomm.colab.ws/publications/10.1070/MC2000v010n06ABEH001337
TI - The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions
T2 - Mendeleev Communications
AU - Zakharova, Lucia Yarullovna
AU - Valeeva, Farida Garafeevna
AU - Kudryavtseva, Lyudmila Andreevna
AU - Konovalov, Aleksandr Ivanovich
PY - 2000
DA - 2000/12/07
PB - Mendeleev Communications
SP - 241-243
IS - 6
VL - 10
ER -
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@article{2000_Zakharova,
author = {Lucia Yarullovna Zakharova and Farida Garafeevna Valeeva and Lyudmila Andreevna Kudryavtseva and Aleksandr Ivanovich Konovalov},
title = {The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions},
journal = {Mendeleev Communications},
year = {2000},
volume = {10},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2000v010n06ABEH001337},
number = {6},
pages = {241--243},
doi = {10.1070/MC2000v010n06ABEH001337}
}
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Zakharova, Lucia Yarullovna, et al. “The kinetics of solvolysis of p-nitrophenyl bis(chloromethyl)phosphinate in a micellar solution of sodium dodecyl sulfate in ethylene glycol: catalysis by metal ions.” Mendeleev Communications, vol. 10, no. 6, Dec. 2000, pp. 241-243. https://mendcomm.colab.ws/publications/10.1070/MC2000v010n06ABEH001337.

Abstract

A 30-fold acceleration of the title reaction due to an increase in the activation entropy and activation enthalpy in the micellar pseudophase compared to ethylene glycol was found; Mg2+, Zn2+ and La3+ ions accelerate the solvolysis by factors of 5, 8 and 20, respectively.

References

1.
10.1070/MC2000v010n06ABEH001337_bib1
Bunton
Adv. Phys. Chem., 1986
3.
10.1070/MC2000v010n06ABEH001337_bib3
Martinek
1977
4.
10.1070/MC2000v010n06ABEH001337_bib4
Shinoda
Colloidal Surfactants, 1963
6.
A. I. Rusanov, Mitselloobrazovanie v rastvorakh poverkhnostno-aktivnykh veshchestv (Micellization in the solutions of the surface-active substances), Khimiya, St. Petersburg, 1992.
9.
10.1070/MC2000v010n06ABEH001337_bib9
Eychenne
New J. Chem., 1995
11.
10.1070/MC2000v010n06ABEH001337_bib11
Bunton
J. Chem. Soc., Perkin Trans., 1975
12.
10.1070/MC2000v010n06ABEH001337_bib12
Bel'skii
Izv. Akad. Nauk SSSR, Ser. Khim., 1967
13.
Problem of pH in micellar catalyzed reactions
Bunton C.A., Wolfe B.
Journal of the American Chemical Society, 1973
14.
10.1070/MC2000v010n06ABEH001337_bib14
Bel'skii
Zh. Obshch. Khim., 1970
15.
10.1070/MC2000v010n06ABEH001337_bib15
Hoffmann
Aufklarung von Reactionsmechanismen, 1976
16.
10.1070/MC2000v010n06ABEH001337_bib16
Ingold
Structure and Mechanism in Organic Chemistry, 1969
17.
N. A. Loshadkin, in Toksichnye efiry kislot fosfora (Toxic Esters of Phosphorus Acids), ed. P. O’Brain, Mir, Moscow, 1964 (in Russian).
18.
10.1070/MC2000v010n06ABEH001337_bib18
Bunton
Reaction Kinetics in Micelles, 1973
19.
Zakharova L.Y., Kudryavtsev D.B., Kudryavtseva L.A., Konovalov A.I., Zuev Y.F., Vylegzhanina N.N., Zakharchenko N.L., Idiatullin Z.S.
Mendeleev Communications, 1999
20.
10.1070/MC2000v010n06ABEH001337_bib20
Jencks
Catalysis in Chemistry and Enzymology, 1969