Abstract
2-Polyfluoroalkylchromones react with 2-aminoethanol at room temperature to give either 3-(2-hydroxyethylamino)-1-(2-hydroxyphenyl)-3-polyfluoroalkylprop-2-en-1-ones [RF = CF2H, CF3, (CF2)2OCF3 or (CF2)3CF3] or N-(2-hydroxyethyl)-2-polyfluoroalkyl-4H-chromene-4-imines [RF = (CF2)2H or C2F5].
References
1.
10.1070/MC2000v010n06ABEH001310_bib1
Kostka
Roczn. Chem.,
1966
2.
10.1070/MC2000v010n06ABEH001310_bib2
Elkaschef
Indian J. Chem.,
1973
3.
Steric factor in reactions of substituted 2-trifluoromethylchromones with ammonia and primary amines
Sosnovskikh V.Y., Kutsenko V.A., Yachevskii D.S.
Mendeleev Communications,
1999
4.
Sosnovskikh V.Y., Kutsenko V.A., Morozov M.Y.
Mendeleev Communications,
1998