Home / Publications / Aromatic stabilization of organochalcogen compounds with the intramolecular X←O (X = S, Se, Te) coordination

Aromatic stabilization of organochalcogen compounds with the intramolecular X←O (X = S, Se, Te) coordination

Vladimir Isaakovich Minkin 1
Vladimir Isaakovich Minkin
, 
Ruslan Mikhailovich Minyaev 1
Ruslan Mikhailovich Minyaev
10.1070/MC2000v010n05ABEH001349
Published 2000-10-13
Communication , Volume 10, Issue 5, 171-173
11
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Minkin V. I., Minyaev R. M. Aromatic stabilization of organochalcogen compounds with the intramolecular X←O (X = S, Se, Te) coordination // Mendeleev Communications. 2000. Vol. 10. No. 5. pp. 171-173.
GOST all authors (up to 50) Copy
Minkin V. I., Minyaev R. M. Aromatic stabilization of organochalcogen compounds with the intramolecular X←O (X = S, Se, Te) coordination // Mendeleev Communications. 2000. Vol. 10. No. 5. pp. 171-173.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2000v010n05ABEH001349
UR - https://mendcomm.colab.ws/publications/10.1070/MC2000v010n05ABEH001349
TI - Aromatic stabilization of organochalcogen compounds with the intramolecular X←O (X = S, Se, Te) coordination
T2 - Mendeleev Communications
AU - Minkin, Vladimir Isaakovich
AU - Minyaev, Ruslan Mikhailovich
PY - 2000
DA - 2000/10/13
PB - Mendeleev Communications
SP - 171-173
IS - 5
VL - 10
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2000_Minkin,
author = {Vladimir Isaakovich Minkin and Ruslan Mikhailovich Minyaev},
title = {Aromatic stabilization of organochalcogen compounds with the intramolecular X←O (X = S, Se, Te) coordination},
journal = {Mendeleev Communications},
year = {2000},
volume = {10},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2000v010n05ABEH001349},
number = {5},
pages = {171--173},
doi = {10.1070/MC2000v010n05ABEH001349}
}
MLA
Cite this
MLA Copy
Minkin, Vladimir Isaakovich, and Ruslan Mikhailovich Minyaev. “Aromatic stabilization of organochalcogen compounds with the intramolecular X←O (X = S, Se, Te) coordination.” Mendeleev Communications, vol. 10, no. 5, Oct. 2000, pp. 171-173. https://mendcomm.colab.ws/publications/10.1070/MC2000v010n05ABEH001349.

Abstract

The ab initio MP2/LanL2DZ calculations predict a significant contribution of cyclic π-electron delocalization to the stabilization of the trans–cis–cis conformation of derivatives of β-chalcogenovinylaldehydes 1 with the intramolecular Chalc←O coordination.

References

1.
Bonding between nonbonded sulfur and oxygen atoms in selected organic molecules (a quantum chemical study)
Angyan J.G., Poirier R.A., Kucsman A., Csizmadia I.G.
Journal of the American Chemical Society, 1987
2.
Unusual attractive interactions between selenium and oxygen in selenoiminoquinones
Barton D.H., Hall M.B., Lin Z., Parekh S.I., Reibenspies J.
Journal of the American Chemical Society, 1993
4.
10.1070/MC2000v010n05ABEH001349_bib4
Minkin
Ross. Khim. Zh., 1999
5.
10.1070/MC2000v010n05ABEH001349_bib5
Kucsman
Organic Sulfur Chemistry: Theoretical and Experimental Advances, 1985
6.
Theoretical study of O - > X (S, Se, Te) coordination in organic compounds
Minyaev R.M., Minkin V.I.
Canadian Journal of Chemistry, 1998
7.
Low coordinate hypervalent phosphorus
Arduengo A.J., Stewart C.A.
Chemical Reviews, 1994
8.
Hypervalent Bond Formation in Halogeno(2-acylphenyl)bismuthanes
Murafuji T., Mutoh T., Satoh K., Tsunenari K., Azuma N., Suzuki H.
Organometallics, 1995
10.
Intramolecular Nonbonded S···O Interaction Recognized in (Acylimino)thiadiazoline Derivatives as Angiotensin II Receptor Antagonists and Related Compounds
Nagao Y., Hirata T., Goto S., Sano S., Kakehi A., Iizuka K., Shiro M.
Journal of the American Chemical Society, 1998
11.
10.1070/MC2000v010n05ABEH001349_bib11
Minkin
Aromaticity and Antiaromaticity: Electronic and Structural Aspects, 1994
12.
van der Waals Volumes and Radii
Bondi A.
The Journal of Physical Chemistry, 1964
13.
Correlation effects in the ab initio thermochemistry of benzene
Disch R.L., Schulman J.M.
Chemical Physics Letters, 1988
14.
Cyclization of 3-(arylchalcogeno)propenoyl chlorides. 1. 1,2-Oxatellurol-1-ium halides via ipso acylation
Detty M.R., Murray B.J., Smith D.L., Zumbulyadis N.
Journal of the American Chemical Society, 1983