Home / Publications / Reaction of [(PPh3)3RuCl2] with white phosphorus: synthesis of the first RuII complex featuring a tetrahedro-tetraphosphorus ligand

Reaction of [(PPh3)3RuCl2] with white phosphorus: synthesis of the first RuII complex featuring a tetrahedro-tetraphosphorus ligand

Maurizio Peruzzini 1
Maurizio Peruzzini
, 
Sonia Manas 2
Sonia Manas
, 
Antonio Romerosa 2
Antonio Romerosa
, 
Alberto Vacca 3
Alberto Vacca
1 Istituto per lo studio della stereochimica ed energetica dei composti di coordinazione-CNR, Florence, Italy
10.1070/MC2000v010n04ABEH001271
Published 2000-07-31
Communication , Volume 10, Issue 4, 134-135
10
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Peruzzini M. et al. Reaction of [(PPh3)3RuCl2] with white phosphorus: synthesis of the first RuII complex featuring a tetrahedro-tetraphosphorus ligand // Mendeleev Communications. 2000. Vol. 10. No. 4. pp. 134-135.
GOST all authors (up to 50) Copy
Peruzzini M., Manas S., Romerosa A., Vacca A. Reaction of [(PPh3)3RuCl2] with white phosphorus: synthesis of the first RuII complex featuring a tetrahedro-tetraphosphorus ligand // Mendeleev Communications. 2000. Vol. 10. No. 4. pp. 134-135.
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TY - JOUR
DO - 10.1070/MC2000v010n04ABEH001271
UR - https://mendcomm.colab.ws/publications/10.1070/MC2000v010n04ABEH001271
TI - Reaction of [(PPh3)3RuCl2] with white phosphorus: synthesis of the first RuII complex featuring a tetrahedro-tetraphosphorus ligand
T2 - Mendeleev Communications
AU - Peruzzini, Maurizio
AU - Manas, Sonia
AU - Romerosa, Antonio
AU - Vacca, Alberto
PY - 2000
DA - 2000/07/31
PB - Mendeleev Communications
SP - 134-135
IS - 4
VL - 10
ER -
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@article{2000_Peruzzini,
author = {Maurizio Peruzzini and Sonia Manas and Antonio Romerosa and Alberto Vacca},
title = {Reaction of [(PPh3)3RuCl2] with white phosphorus: synthesis of the first RuII complex featuring a tetrahedro-tetraphosphorus ligand},
journal = {Mendeleev Communications},
year = {2000},
volume = {10},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2000v010n04ABEH001271},
number = {4},
pages = {134--135},
doi = {10.1070/MC2000v010n04ABEH001271}
}
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Peruzzini, Maurizio, et al. “Reaction of [(PPh3)3RuCl2] with white phosphorus: synthesis of the first RuII complex featuring a tetrahedro-tetraphosphorus ligand.” Mendeleev Communications, vol. 10, no. 4, Jul. 2000, pp. 134-135. https://mendcomm.colab.ws/publications/10.1070/MC2000v010n04ABEH001271.

Abstract

The title reaction affords slightly air- and light-sensitive [(PPh3)2ClRu(μ-Cl)3Ru(PPh3)2(η1-P4)], which belongs to a very rare family of soluble tetrahedro-tetraphosphorus complexes and represents the first ruthenium species of this type.

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