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Synthesis and thermal decomposition of organosilicon hexamine cobalt-containing xerogels

Vladimir Viktorovich Semenov 1
Vladimir Viktorovich Semenov
Larisa Grigor'evna Klapshina 1
Larisa Grigor'evna Klapshina
William Eliot Douglas 2
William Eliot Douglas
Georgy Alekseevich Domrachev 1
Georgy Alekseevich Domrachev
Published 2000-07-31
CommunicationVolume 10, Issue 4, 157-159
8
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Semenov V. V. et al. Synthesis and thermal decomposition of organosilicon hexamine cobalt-containing xerogels // Mendeleev Communications. 2000. Vol. 10. No. 4. pp. 157-159.
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Semenov V. V., Klapshina L. G., Douglas W. E., Domrachev G. A. Synthesis and thermal decomposition of organosilicon hexamine cobalt-containing xerogels // Mendeleev Communications. 2000. Vol. 10. No. 4. pp. 157-159.
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TY - JOUR
DO - 10.1070/MC2000v010n04ABEH001221
UR - https://mendcomm.colab.ws/publications/10.1070/MC2000v010n04ABEH001221
TI - Synthesis and thermal decomposition of organosilicon hexamine cobalt-containing xerogels
T2 - Mendeleev Communications
AU - Semenov, Vladimir Viktorovich
AU - Klapshina, Larisa Grigor'evna
AU - Douglas, William Eliot
AU - Domrachev, Georgy Alekseevich
PY - 2000
DA - 2000/07/31
PB - Mendeleev Communications
SP - 157-159
IS - 4
VL - 10
ER -
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@article{2000_Semenov,
author = {Vladimir Viktorovich Semenov and Larisa Grigor'evna Klapshina and William Eliot Douglas and Georgy Alekseevich Domrachev},
title = {Synthesis and thermal decomposition of organosilicon hexamine cobalt-containing xerogels},
journal = {Mendeleev Communications},
year = {2000},
volume = {10},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2000v010n04ABEH001221},
number = {4},
pages = {157--159},
doi = {10.1070/MC2000v010n04ABEH001221}
}
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Semenov, Vladimir Viktorovich, et al. “Synthesis and thermal decomposition of organosilicon hexamine cobalt-containing xerogels.” Mendeleev Communications, vol. 10, no. 4, Jul. 2000, pp. 157-159. https://mendcomm.colab.ws/publications/10.1070/MC2000v010n04ABEH001221.

Abstract

The treatment of 3-aminopropyltriethoxysilane (APTES) with Co2(CO)8 resulted in hexa(3-aminopropyltriethoxysilane)cobalt(II) bis(tetracarbonylcobaltate) 1, the co-hydrolysis of which with APTES, tetraethoxysilane, MeSi(OMe)3 and HO(Me2SiO)nOH afforded cobalt-containing xerogels or transparent films.

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