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Alkene–alkyne metathesis and 1,4-cis-hydrogenation as a route to tetrasubstituted (Z)-olefins

Andrei Alexandrovich Vasil'ev 1
Andrei Alexandrovich Vasil'ev
, 
Lars Engman 2
Lars Engman
, 
Edward Prokof'evich Serebryakov 1
Edward Prokof'evich Serebryakov
10.1070/MC2000v010n03ABEH001303
Published 2000-06-07
Communication , Volume 10, Issue 3, 101-103
6
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Vasil'ev A. A., Engman L., Serebryakov E. P. Alkene–alkyne metathesis and 1,4-cis-hydrogenation as a route to tetrasubstituted (Z)-olefins // Mendeleev Communications. 2000. Vol. 10. No. 3. pp. 101-103.
GOST all authors (up to 50) Copy
Vasil'ev A. A., Engman L., Serebryakov E. P. Alkene–alkyne metathesis and 1,4-cis-hydrogenation as a route to tetrasubstituted (Z)-olefins // Mendeleev Communications. 2000. Vol. 10. No. 3. pp. 101-103.
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TY - JOUR
DO - 10.1070/MC2000v010n03ABEH001303
UR - https://mendcomm.colab.ws/publications/10.1070/MC2000v010n03ABEH001303
TI - Alkene–alkyne metathesis and 1,4-cis-hydrogenation as a route to tetrasubstituted (Z)-olefins
T2 - Mendeleev Communications
AU - Vasil'ev, Andrei Alexandrovich
AU - Engman, Lars
AU - Serebryakov, Edward Prokof'evich
PY - 2000
DA - 2000/06/07
PB - Mendeleev Communications
SP - 101-103
IS - 3
VL - 10
ER -
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@article{2000_Vasil'ev,
author = {Andrei Alexandrovich Vasil'ev and Lars Engman and Edward Prokof'evich Serebryakov},
title = {Alkene–alkyne metathesis and 1,4-cis-hydrogenation as a route to tetrasubstituted (Z)-olefins},
journal = {Mendeleev Communications},
year = {2000},
volume = {10},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2000v010n03ABEH001303},
number = {3},
pages = {101--103},
doi = {10.1070/MC2000v010n03ABEH001303}
}
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Vasil'ev, Andrei Alexandrovich, et al. “Alkene–alkyne metathesis and 1,4-cis-hydrogenation as a route to tetrasubstituted (Z)-olefins.” Mendeleev Communications, vol. 10, no. 3, Jun. 2000, pp. 101-103. https://mendcomm.colab.ws/publications/10.1070/MC2000v010n03ABEH001303.

Abstract

Stereospecific synthesis of erythro-5-benzyloxy-2,3-dimethylpentan-1-ol, a building block for the preparation of faranal and lasiol,was performed starting from 5-benzyloxypent-2-yn-1-ol using the title methodology followed by 1,2-syn-hydrogenation.

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