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Effect of proton donors on the mechanism of electroreduction of α-radicals of linear and cyclic ethers

Alexander Georgievich Krivenko 1
Alexander Georgievich Krivenko
, 
Alexander Semenovich Kotkin 1
Alexander Semenovich Kotkin
, 
Vladimir Alexandrovich Kurmaz 1
Vladimir Alexandrovich Kurmaz
10.1070/MC2000v010n02ABEH001254
Published 2000-03-30
Communication , Volume 10, Issue 2, 46-49
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Krivenko A. G., Kotkin A. S., Kurmaz V. A. Effect of proton donors on the mechanism of electroreduction of α-radicals of linear and cyclic ethers // Mendeleev Communications. 2000. Vol. 10. No. 2. pp. 46-49.
GOST all authors (up to 50) Copy
Krivenko A. G., Kotkin A. S., Kurmaz V. A. Effect of proton donors on the mechanism of electroreduction of α-radicals of linear and cyclic ethers // Mendeleev Communications. 2000. Vol. 10. No. 2. pp. 46-49.
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TY - JOUR
DO - 10.1070/MC2000v010n02ABEH001254
UR - https://mendcomm.colab.ws/publications/10.1070/MC2000v010n02ABEH001254
TI - Effect of proton donors on the mechanism of electroreduction of α-radicals of linear and cyclic ethers
T2 - Mendeleev Communications
AU - Krivenko, Alexander Georgievich
AU - Kotkin, Alexander Semenovich
AU - Kurmaz, Vladimir Alexandrovich
PY - 2000
DA - 2000/03/30
PB - Mendeleev Communications
SP - 46-49
IS - 2
VL - 10
ER -
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@article{2000_Krivenko,
author = {Alexander Georgievich Krivenko and Alexander Semenovich Kotkin and Vladimir Alexandrovich Kurmaz},
title = {Effect of proton donors on the mechanism of electroreduction of α-radicals of linear and cyclic ethers},
journal = {Mendeleev Communications},
year = {2000},
volume = {10},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2000v010n02ABEH001254},
number = {2},
pages = {46--49},
doi = {10.1070/MC2000v010n02ABEH001254}
}
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Krivenko, Alexander Georgievich, et al. “Effect of proton donors on the mechanism of electroreduction of α-radicals of linear and cyclic ethers.” Mendeleev Communications, vol. 10, no. 2, Mar. 2000, pp. 46-49. https://mendcomm.colab.ws/publications/10.1070/MC2000v010n02ABEH001254.

Abstract

Using laser photoemission, we found two routes of the electroreduction of α-radicals (Rads) adsorbed on a mercury electrode for linear and cyclic ethers in the presence of strong proton donors (BH+), i.e., by direct one-electron transfer and with the antecedent formation of the metastable complex [Rads·BH+]

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