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Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines

Victor Andreevich Bagryansky 1
Victor Andreevich Bagryansky
, 
Ivan Valeryevich Vlasyuk 2
Ivan Valeryevich Vlasyuk
, 
Yuriy Vasil'evich Gatilov 3
Yuriy Vasil'evich Gatilov
, 
Alexander Yur'evich Makarov 3
Alexander Yur'evich Makarov
, 
Yuri Nikolaevich Molin 1
Yuri Nikolaevich Molin
, 
Vladimir Vladimirovich Shcherbukhin 4
Vladimir Vladimirovich Shcherbukhin
, 
Andrey Viktorovich Zibarev 3
Andrey Viktorovich Zibarev
10.1070/MC2000v010n01ABEH001198
Published 2000-01-27
Communication , Volume 10, Issue 1, 5-7
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Bagryansky V. A. et al. Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines // Mendeleev Communications. 2000. Vol. 10. No. 1. pp. 5-7.
GOST all authors (up to 50) Copy
Bagryansky V. A., Vlasyuk I. V., Gatilov Y. V., Makarov A. Y., Molin Y. N., Shcherbukhin V. V., Zibarev A. V. Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines // Mendeleev Communications. 2000. Vol. 10. No. 1. pp. 5-7.
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TY - JOUR
DO - 10.1070/MC2000v010n01ABEH001198
UR - https://mendcomm.colab.ws/publications/10.1070/MC2000v010n01ABEH001198
TI - Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines
T2 - Mendeleev Communications
AU - Bagryansky, Victor Andreevich
AU - Vlasyuk, Ivan Valeryevich
AU - Gatilov, Yuriy Vasil'evich
AU - Makarov, Alexander Yur'evich
AU - Molin, Yuri Nikolaevich
AU - Shcherbukhin, Vladimir Vladimirovich
AU - Zibarev, Andrey Viktorovich
PY - 2000
DA - 2000/01/27
PB - Mendeleev Communications
SP - 5-7
IS - 1
VL - 10
ER -
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@article{2000_Bagryansky,
author = {Victor Andreevich Bagryansky and Ivan Valeryevich Vlasyuk and Yuriy Vasil'evich Gatilov and Alexander Yur'evich Makarov and Yuri Nikolaevich Molin and Vladimir Vladimirovich Shcherbukhin and Andrey Viktorovich Zibarev},
title = {Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines},
journal = {Mendeleev Communications},
year = {2000},
volume = {10},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2000v010n01ABEH001198},
number = {1},
pages = {5--7},
doi = {10.1070/MC2000v010n01ABEH001198}
}
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Bagryansky, Victor Andreevich, et al. “Formation of stable 1,2,3-benzodithiazolyl radicals by thermolysis of 1,3,2,4-benzodithiadiazines.” Mendeleev Communications, vol. 10, no. 1, Jan. 2000, pp. 5-7. https://mendcomm.colab.ws/publications/10.1070/MC2000v010n01ABEH001198.

Abstract

Mild thermolysis (at 110–150 °C) of 1,3,2,4-benzodithiadiazine 1 and its derivatives 2–6 in hydrocarbon solvents quantitatively yielded stable 1,2,3-benzodithiazolyl π-radicals via a first-order reaction (Ea = 76.2 kJ mol–1, k0 = 4.34×105 s–1 for 1).

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