Home / Publications / Photoinduced activation of arene C–H bonds with (η5-cyclopentadienyl)-trimethylplatinum(IV): a possible role of CpPtR2H

Photoinduced activation of arene C–H bonds with (η5-cyclopentadienyl)-trimethylplatinum(IV): a possible role of CpPtR2H

Andrei Nikolaevich Vedernikov 1
Andrei Nikolaevich Vedernikov
, 
Sergei Vladimirovich Borisoglebski 1
Sergei Vladimirovich Borisoglebski
, 
Alexei Borisovich Solomonov 1
Alexei Borisovich Solomonov
, 
Boris Nikolaevich Solomonov 1
Boris Nikolaevich Solomonov
10.1070/MC2000v010n01ABEH001168
Published 2000-01-27
Communication , Volume 10, Issue 1, 20-21
7
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Vedernikov A. N. et al. Photoinduced activation of arene C–H bonds with (η5-cyclopentadienyl)-trimethylplatinum(IV): a possible role of CpPtR2H // Mendeleev Communications. 2000. Vol. 10. No. 1. pp. 20-21.
GOST all authors (up to 50) Copy
Vedernikov A. N., Borisoglebski S. V., Solomonov A. B., Solomonov B. N. Photoinduced activation of arene C–H bonds with (η5-cyclopentadienyl)-trimethylplatinum(IV): a possible role of CpPtR2H // Mendeleev Communications. 2000. Vol. 10. No. 1. pp. 20-21.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC2000v010n01ABEH001168
UR - https://mendcomm.colab.ws/publications/10.1070/MC2000v010n01ABEH001168
TI - Photoinduced activation of arene C–H bonds with (η5-cyclopentadienyl)-trimethylplatinum(IV): a possible role of CpPtR2H
T2 - Mendeleev Communications
AU - Vedernikov, Andrei Nikolaevich
AU - Borisoglebski, Sergei Vladimirovich
AU - Solomonov, Alexei Borisovich
AU - Solomonov, Boris Nikolaevich
PY - 2000
DA - 2000/01/27
PB - Mendeleev Communications
SP - 20-21
IS - 1
VL - 10
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2000_Vedernikov,
author = {Andrei Nikolaevich Vedernikov and Sergei Vladimirovich Borisoglebski and Alexei Borisovich Solomonov and Boris Nikolaevich Solomonov},
title = {Photoinduced activation of arene C–H bonds with (η5-cyclopentadienyl)-trimethylplatinum(IV): a possible role of CpPtR2H},
journal = {Mendeleev Communications},
year = {2000},
volume = {10},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2000v010n01ABEH001168},
number = {1},
pages = {20--21},
doi = {10.1070/MC2000v010n01ABEH001168}
}
MLA
Cite this
MLA Copy
Vedernikov, Andrei Nikolaevich, et al. “Photoinduced activation of arene C–H bonds with (η5-cyclopentadienyl)-trimethylplatinum(IV): a possible role of CpPtR2H.” Mendeleev Communications, vol. 10, no. 1, Jan. 2000, pp. 20-21. https://mendcomm.colab.ws/publications/10.1070/MC2000v010n01ABEH001168.

Abstract

(η5-Cyclopentadienyl)trimethylplatinum(IV) reacts with ArMe arenes rather than alkanes or benzene under heating to 150 °C in the dark or under irradiation with light at room temperature by a radical mechanism to produce (η5-cyclopentadienyl)dimethyl-(arylmethyl)platinum(IV) complexes, and the expected complex CpPtR2(H) is unstable under the reaction conditions, as found by the reduction of CpPtMe2I with complex metal hydrides.

References

2.
10.1070/MC2000v010n01ABEH001168_bib2
Vedernikov
Zh. Obshch. Khim., 1998
3.
Solid-State Structure of Tp‘PtMe2H, a Dimethylhydrido Platinum(IV) Complex
O'Reilly S.A., White P.S., Templeton J.L.
Journal of the American Chemical Society, 1996
5.
C−H Activation at Pt(II) To Form Stable Pt(IV) Alkyl Hydrides
Wick D.D., Goldberg K.I.
Journal of the American Chemical Society, 1997
6.
Cationic Methyl(hydrido)platinum(IV) Complexes
Jenkins H.A., Yap G.P., Puddephatt R.J.
Organometallics, 1997
10.
Preparation of some cyclopentadienyl platinum (IV) complexes
Shaver A.
Canadian Journal of Chemistry, 1978
11.
Selective sp3 CH bond activation of alkylaromatics promoted by platinum complexes
Miyashita A., Hotta M., Saida Y.
Journal of Organometallic Chemistry, 1994