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A new procedure for estimating the enthalpies of formation for RCH2·free radicals

Yurii Dmitrievich Orlov 1
Yurii Dmitrievich Orlov
, 
Vyacheslav Vasil'evich Takhistov 2
Vyacheslav Vasil'evich Takhistov
2 St. Petersburg Scientific Centre of Ecological Safety, Russian Academy of Sciences, St. Petersburg, Russian Federation
10.1070/MC2000v010n01ABEH001122
Published 2000-01-27
Communication , Volume 10, Issue 1, 23-25
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Orlov Y. D., Takhistov V. V. A new procedure for estimating the enthalpies of formation for RCH2·free radicals // Mendeleev Communications. 2000. Vol. 10. No. 1. pp. 23-25.
GOST all authors (up to 50) Copy
Orlov Y. D., Takhistov V. V. A new procedure for estimating the enthalpies of formation for RCH2·free radicals // Mendeleev Communications. 2000. Vol. 10. No. 1. pp. 23-25.
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TY - JOUR
DO - 10.1070/MC2000v010n01ABEH001122
UR - https://mendcomm.colab.ws/publications/10.1070/MC2000v010n01ABEH001122
TI - A new procedure for estimating the enthalpies of formation for RCH2·free radicals
T2 - Mendeleev Communications
AU - Orlov, Yurii Dmitrievich
AU - Takhistov, Vyacheslav Vasil'evich
PY - 2000
DA - 2000/01/27
PB - Mendeleev Communications
SP - 23-25
IS - 1
VL - 10
ER -
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@article{2000_Orlov,
author = {Yurii Dmitrievich Orlov and Vyacheslav Vasil'evich Takhistov},
title = {A new procedure for estimating the enthalpies of formation for RCH2·free radicals},
journal = {Mendeleev Communications},
year = {2000},
volume = {10},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1070/MC2000v010n01ABEH001122},
number = {1},
pages = {23--25},
doi = {10.1070/MC2000v010n01ABEH001122}
}
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Orlov, Yurii Dmitrievich, and Vyacheslav Vasil'evich Takhistov. “A new procedure for estimating the enthalpies of formation for RCH2·free radicals.” Mendeleev Communications, vol. 10, no. 1, Jan. 2000, pp. 23-25. https://mendcomm.colab.ws/publications/10.1070/MC2000v010n01ABEH001122.

Abstract

From the observed regularity that for certain substituents the ΔΔHf0 values for Me• → RCH2• free radicals and CH2=CH2 → → RCH=CH2 molecules are nearly identical, new or corrected values for the enthalpies of formation were estimated for about 30 gaseous free radicals and molecules.

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