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Cyclic (4S)-chloromethyl sulfite and sulfate derivatives of (S)-glycidol as valuable synthetic equivalents of scalemic epichlorohydrin

Alexander Alexandrovich Bredikhin 1
Alexander Alexandrovich Bredikhin
, 
Sergey N Lazarev 1
Sergey N Lazarev
, 
Alexander Vladimirovich Pashagin 1
Alexander Vladimirovich Pashagin
, 
Zemfira Azal'evna Bredikhina 1
Zemfira Azal'evna Bredikhina
10.1070/MC1999v009n06ABEH001190
Published 1999-11-25
Communication , Volume 9, Issue 6, 236-238
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Bredikhin A. A. et al. Cyclic (4S)-chloromethyl sulfite and sulfate derivatives of (S)-glycidol as valuable synthetic equivalents of scalemic epichlorohydrin // Mendeleev Communications. 1999. Vol. 9. No. 6. pp. 236-238.
GOST all authors (up to 50) Copy
Bredikhin A. A., Lazarev S. N., Pashagin A. V., Bredikhina Z. A. Cyclic (4S)-chloromethyl sulfite and sulfate derivatives of (S)-glycidol as valuable synthetic equivalents of scalemic epichlorohydrin // Mendeleev Communications. 1999. Vol. 9. No. 6. pp. 236-238.
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TY - JOUR
DO - 10.1070/MC1999v009n06ABEH001190
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n06ABEH001190
TI - Cyclic (4S)-chloromethyl sulfite and sulfate derivatives of (S)-glycidol as valuable synthetic equivalents of scalemic epichlorohydrin
T2 - Mendeleev Communications
AU - Bredikhin, Alexander Alexandrovich
AU - Lazarev, Sergey N
AU - Pashagin, Alexander Vladimirovich
AU - Bredikhina, Zemfira Azal'evna
PY - 1999
DA - 1999/11/25
PB - Mendeleev Communications
SP - 236-238
IS - 6
VL - 9
ER -
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@article{1999_Bredikhin,
author = {Alexander Alexandrovich Bredikhin and Sergey N Lazarev and Alexander Vladimirovich Pashagin and Zemfira Azal'evna Bredikhina},
title = {Cyclic (4S)-chloromethyl sulfite and sulfate derivatives of (S)-glycidol as valuable synthetic equivalents of scalemic epichlorohydrin},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n06ABEH001190},
number = {6},
pages = {236--238},
doi = {10.1070/MC1999v009n06ABEH001190}
}
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Bredikhin, Alexander Alexandrovich, et al. “Cyclic (4S)-chloromethyl sulfite and sulfate derivatives of (S)-glycidol as valuable synthetic equivalents of scalemic epichlorohydrin.” Mendeleev Communications, vol. 9, no. 6, Nov. 1999, pp. 236-238. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n06ABEH001190.

Abstract

The interaction of (S)-glycidol with SOCl2 or SO2Cl2 in stoichiometric amounts leads to the formation of cyclic (4S)-chloromethyl sulfite or sulfate derivatives with the same enantiomeric purity; based on this reaction, a new procedure for the synthesis of (S)-propranolol was developed.

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