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Manganese tetraazaporphines as effective catalysts for the nuclear oxidation of aromatics by peracetic acid

Svetlana Vasil'evna Barkanova 1
Svetlana Vasil'evna Barkanova
, 
Elena Aleksandrovna Makarova 1
Elena Aleksandrovna Makarova
, 
Oleg Leonidovich Kaliya 1
Oleg Leonidovich Kaliya
, 
Evgenii Antonovich Luk'yanets 1
Evgenii Antonovich Luk'yanets
10.1070/MC1999v009n05ABEH001165
Published 1999-09-28
Communication , Volume 9, Issue 5, 177-179
12
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Barkanova S. V. et al. Manganese tetraazaporphines as effective catalysts for the nuclear oxidation of aromatics by peracetic acid // Mendeleev Communications. 1999. Vol. 9. No. 5. pp. 177-179.
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Barkanova S. V., Makarova E. A., Kaliya O. L., Luk'yanets E. A. Manganese tetraazaporphines as effective catalysts for the nuclear oxidation of aromatics by peracetic acid // Mendeleev Communications. 1999. Vol. 9. No. 5. pp. 177-179.
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TY - JOUR
DO - 10.1070/MC1999v009n05ABEH001165
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001165
TI - Manganese tetraazaporphines as effective catalysts for the nuclear oxidation of aromatics by peracetic acid
T2 - Mendeleev Communications
AU - Barkanova, Svetlana Vasil'evna
AU - Makarova, Elena Aleksandrovna
AU - Kaliya, Oleg Leonidovich
AU - Luk'yanets, Evgenii Antonovich
PY - 1999
DA - 1999/09/28
PB - Mendeleev Communications
SP - 177-179
IS - 5
VL - 9
ER -
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@article{1999_Barkanova,
author = {Svetlana Vasil'evna Barkanova and Elena Aleksandrovna Makarova and Oleg Leonidovich Kaliya and Evgenii Antonovich Luk'yanets},
title = {Manganese tetraazaporphines as effective catalysts for the nuclear oxidation of aromatics by peracetic acid},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001165},
number = {5},
pages = {177--179},
doi = {10.1070/MC1999v009n05ABEH001165}
}
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Barkanova, Svetlana Vasil'evna, et al. “Manganese tetraazaporphines as effective catalysts for the nuclear oxidation of aromatics by peracetic acid.” Mendeleev Communications, vol. 9, no. 5, Sep. 1999, pp. 177-179. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001165.

Abstract

Manganese tetranitrotetra-tert-butyltetraazaporphine at low concentrations (0.02 mol%) effectively catalyses the oxidation of 2-methylnaphthalene by peracetic acid to give 2-methyl-1,4-naphthoquinone in 65% yield with a catalyst turnover number of 3100.

References

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Homogeneous oxidation of aromatics in nucleus with peracetic acid catalyzed by iron and manganese phthalocyanine complexes
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Tetrahedron Letters, 1995
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