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The first efficient electrophilic carbonylation of ethane with carbon monoxide

Alexander Vyacheslavovich Orlinkov 1
Alexander Vyacheslavovich Orlinkov
Irena Sergeevna Akhrem 1
Irena Sergeevna Akhrem
Sergei Vladimirovich Vitt 1
Sergei Vladimirovich Vitt
Published 1999-09-28
CommunicationVolume 9, Issue 5, 198-199
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Orlinkov A. V., Akhrem I. S., Vitt S. V. The first efficient electrophilic carbonylation of ethane with carbon monoxide // Mendeleev Communications. 1999. Vol. 9. No. 5. pp. 198-199.
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Orlinkov A. V., Akhrem I. S., Vitt S. V. The first efficient electrophilic carbonylation of ethane with carbon monoxide // Mendeleev Communications. 1999. Vol. 9. No. 5. pp. 198-199.
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TY - JOUR
DO - 10.1070/MC1999v009n05ABEH001163
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001163
TI - The first efficient electrophilic carbonylation of ethane with carbon monoxide
T2 - Mendeleev Communications
AU - Orlinkov, Alexander Vyacheslavovich
AU - Akhrem, Irena Sergeevna
AU - Vitt, Sergei Vladimirovich
PY - 1999
DA - 1999/09/28
PB - Mendeleev Communications
SP - 198-199
IS - 5
VL - 9
ER -
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@article{1999_Orlinkov,
author = {Alexander Vyacheslavovich Orlinkov and Irena Sergeevna Akhrem and Sergei Vladimirovich Vitt},
title = {The first efficient electrophilic carbonylation of ethane with carbon monoxide},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001163},
number = {5},
pages = {198--199},
doi = {10.1070/MC1999v009n05ABEH001163}
}
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Orlinkov, Alexander Vyacheslavovich, et al. “The first efficient electrophilic carbonylation of ethane with carbon monoxide.” Mendeleev Communications, vol. 9, no. 5, Sep. 1999, pp. 198-199. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001163.

Abstract

Ethane reacts with CO without solvent in the presence of polyhalomethane·2AlBr3 superelectrophilic systems to form EtCOOR after alcoholysis together with small amounts of corresponding esters of 1- and 2-bromopropanoic acids.

References

1.
10.1070/MC1999v009n05ABEH001163_bib1
Bahrmann
New Syntheses with Carbon Monoxide, 1980
2.
10.1070/MC1999v009n05ABEH001163_bib2
Olah
Activation and Functionalization of Alkanes, 1989
3.
Selective electrophilic activation of alkanes
Sommer J., Bukala J.
Accounts of Chemical Research, 1993
4.
10.1070/MC1999v009n05ABEH001163_bib4
Hogeveen
1973
8.
10.1070/MC1999v009n05ABEH001163_bib8
Akhrem
Izv. Akad. Nauk, Ser. Khim., 1996
9.
The first examples of selective carbonylation of n-butane and n-pentane
Akhrem I., Orlinkov A., Afanas'eva L., Petrovskii P., Vitt S.
Tetrahedron Letters, 1999
10.
Akhrem I.S., Bernadyuk S.Z., Vol’pin M.E.
Mendeleev Communications, 1993
11.
10.1070/MC1999v009n05ABEH001163_bib11
Koch
Org. Synth., 1964