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Close contact distance between hexacyanometallate ions in the course of electron transfer

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Galina Aleksandrovna Tsirlina 2
Galina Aleksandrovna Tsirlina
10.1070/MC1999v009n05ABEH001138
Published 1999-09-28
Communication , Volume 9, Issue 5, 181-182
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Kotov V. Y., Tsirlina G. A. Close contact distance between hexacyanometallate ions in the course of electron transfer // Mendeleev Communications. 1999. Vol. 9. No. 5. pp. 181-182.
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Kotov V. Y., Tsirlina G. A. Close contact distance between hexacyanometallate ions in the course of electron transfer // Mendeleev Communications. 1999. Vol. 9. No. 5. pp. 181-182.
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TY - JOUR
DO - 10.1070/MC1999v009n05ABEH001138
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001138
TI - Close contact distance between hexacyanometallate ions in the course of electron transfer
T2 - Mendeleev Communications
AU - Kotov, Vitalii Yur'evich
AU - Tsirlina, Galina Aleksandrovna
PY - 1999
DA - 1999/09/28
PB - Mendeleev Communications
SP - 181-182
IS - 5
VL - 9
ER -
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@article{1999_Kotov,
author = {Vitalii Yur'evich Kotov and Galina Aleksandrovna Tsirlina},
title = {Close contact distance between hexacyanometallate ions in the course of electron transfer},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001138},
number = {5},
pages = {181--182},
doi = {10.1070/MC1999v009n05ABEH001138}
}
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Kotov, Vitalii Yur'evich, and Galina Aleksandrovna Tsirlina. “Close contact distance between hexacyanometallate ions in the course of electron transfer.” Mendeleev Communications, vol. 9, no. 5, Sep. 1999, pp. 181-182. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001138.

Abstract

On the basis of rate constants of redox reactions and stability constants of anion pairs, the contact distances between hexacyanometallate ions in the course of electron transfer were estimated as 6.7–7.1 Å, these values are comparable with the contact anion–anion distances in solids and subtantially lower than the sum of radii of nonhydrated ions.

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