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Electroinduced oxidative transformation of 2,5-dioxabicyclo[4.4.0]decanes into 5-(1,3-dioxolan-2-yl)- and 5-(dimethoxymethyl)pentanoates

Yurii Nikolaevich Ogibin 1
Yurii Nikolaevich Ogibin
,  , 
Alexey Igorevich Ilovaisky 1
Alexey Igorevich Ilovaisky
, 
Gennady Ivanovich Nikishin 1
Gennady Ivanovich Nikishin
10.1070/MC1999v009n05ABEH001133
Published 1999-09-28
Communication , Volume 9, Issue 5, 194-196
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Ogibin Y. N. et al. Electroinduced oxidative transformation of 2,5-dioxabicyclo[4.4.0]decanes into 5-(1,3-dioxolan-2-yl)- and 5-(dimethoxymethyl)pentanoates // Mendeleev Communications. 1999. Vol. 9. No. 5. pp. 194-196.
GOST all authors (up to 50) Copy
Ogibin Y. N., Terent'ev A. O., Ilovaisky A. I., Nikishin G. I. Electroinduced oxidative transformation of 2,5-dioxabicyclo[4.4.0]decanes into 5-(1,3-dioxolan-2-yl)- and 5-(dimethoxymethyl)pentanoates // Mendeleev Communications. 1999. Vol. 9. No. 5. pp. 194-196.
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TY - JOUR
DO - 10.1070/MC1999v009n05ABEH001133
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001133
TI - Electroinduced oxidative transformation of 2,5-dioxabicyclo[4.4.0]decanes into 5-(1,3-dioxolan-2-yl)- and 5-(dimethoxymethyl)pentanoates
T2 - Mendeleev Communications
AU - Ogibin, Yurii Nikolaevich
AU - Terent'ev, Alexander Olegovich
AU - Ilovaisky, Alexey Igorevich
AU - Nikishin, Gennady Ivanovich
PY - 1999
DA - 1999/09/28
PB - Mendeleev Communications
SP - 194-196
IS - 5
VL - 9
ER -
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@article{1999_Ogibin,
author = {Yurii Nikolaevich Ogibin and Alexander Olegovich Terent'ev and Alexey Igorevich Ilovaisky and Gennady Ivanovich Nikishin},
title = {Electroinduced oxidative transformation of 2,5-dioxabicyclo[4.4.0]decanes into 5-(1,3-dioxolan-2-yl)- and 5-(dimethoxymethyl)pentanoates},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001133},
number = {5},
pages = {194--196},
doi = {10.1070/MC1999v009n05ABEH001133}
}
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Ogibin, Yurii Nikolaevich, et al. “Electroinduced oxidative transformation of 2,5-dioxabicyclo[4.4.0]decanes into 5-(1,3-dioxolan-2-yl)- and 5-(dimethoxymethyl)pentanoates.” Mendeleev Communications, vol. 9, no. 5, Sep. 1999, pp. 194-196. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n05ABEH001133.

Abstract

Anodic oxidation of 2,5-dioxabicyclo[4.4.0]decane 1a, 1-methoxy-2,5-dioxabicyclo[4.4.0]decane 1b and 1-hydroxy-2,5-dioxabicyclo[ 4.4.0]decane 1c in methanol in the presence of tetrabutylammonium fluoroborate as a supporting electrolyte induces the electrooxidative transformation of substrates 1a and 1b into methyl 5-(dimethoxymethyl)pentanoate and of substrate 1c into methyl 5-(1,3-dioxolan-2-yl)pentanoate.

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