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Synthesis and stereochemical features of 2-oxo-3-cyano-1,2-thiaphosphorinanes

Irina Leonovna Odinets 1
Irina Leonovna Odinets
, 
Natalya Mikhailovna Vinogradova 1
Natalya Mikhailovna Vinogradova
, 
Oleg Ivanovich Artyushin 1
Oleg Ivanovich Artyushin
, 
Pavel Vasil'evich Petrovskii 1
Pavel Vasil'evich Petrovskii
, 
Konstantin Alexandrovich Lyssenko 1
Konstantin Alexandrovich Lyssenko
, 
Mikhail Yuvenal'evich Antipin 1
Mikhail Yuvenal'evich Antipin
, 
Tatyana Alekseevna Mastryukova 1
Tatyana Alekseevna Mastryukova
10.1070/MC1999v009n04ABEH001141
Published 1999-07-09
Communication , Volume 9, Issue 4, 158-160
7
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Odinets I. L. et al. Synthesis and stereochemical features of 2-oxo-3-cyano-1,2-thiaphosphorinanes // Mendeleev Communications. 1999. Vol. 9. No. 4. pp. 158-160.
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Odinets I. L., Vinogradova N. M., Artyushin O. I., Petrovskii P. V., Lyssenko K. A., Antipin M. Y., Mastryukova T. A. Synthesis and stereochemical features of 2-oxo-3-cyano-1,2-thiaphosphorinanes // Mendeleev Communications. 1999. Vol. 9. No. 4. pp. 158-160.
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TY - JOUR
DO - 10.1070/MC1999v009n04ABEH001141
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001141
TI - Synthesis and stereochemical features of 2-oxo-3-cyano-1,2-thiaphosphorinanes
T2 - Mendeleev Communications
AU - Odinets, Irina Leonovna
AU - Vinogradova, Natalya Mikhailovna
AU - Artyushin, Oleg Ivanovich
AU - Petrovskii, Pavel Vasil'evich
AU - Lyssenko, Konstantin Alexandrovich
AU - Antipin, Mikhail Yuvenal'evich
AU - Mastryukova, Tatyana Alekseevna
PY - 1999
DA - 1999/07/09
PB - Mendeleev Communications
SP - 158-160
IS - 4
VL - 9
ER -
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@article{1999_Odinets,
author = {Irina Leonovna Odinets and Natalya Mikhailovna Vinogradova and Oleg Ivanovich Artyushin and Pavel Vasil'evich Petrovskii and Konstantin Alexandrovich Lyssenko and Mikhail Yuvenal'evich Antipin and Tatyana Alekseevna Mastryukova},
title = {Synthesis and stereochemical features of 2-oxo-3-cyano-1,2-thiaphosphorinanes},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001141},
number = {4},
pages = {158--160},
doi = {10.1070/MC1999v009n04ABEH001141}
}
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Cite this
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Odinets, Irina Leonovna, et al. “Synthesis and stereochemical features of 2-oxo-3-cyano-1,2-thiaphosphorinanes.” Mendeleev Communications, vol. 9, no. 4, Jul. 1999, pp. 158-160. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001141.

Abstract

The intramolecular Pishchimuka rearrangement of 3-halopropyl-substituted thiophosphorylacetonitriles results in the corresponding 2-oxo-3-cyano-1,2-thiaphosphorinanes as a statistical mixture of two diastereomers, which transforms to an individual diastereomer with time; in benzene solution, the latter turns again into an equilibrium mixture of diastereomers.

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