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Configurations of 1,3-bis(aryl)-1,3-diaza-2-thiaallenes in the crystal state

Irina Yur'evna Bagryanskaya 1
Irina Yur'evna Bagryanskaya
, 
Yuriy Vasil'evich Gatilov 1
Yuriy Vasil'evich Gatilov
, 
Andrey Viktorovich Zibarev 1
Andrey Viktorovich Zibarev
10.1070/MC1999v009n04ABEH001140
Published 1999-07-09
Communication , Volume 9, Issue 4, 157-158
9
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Bagryanskaya I. Y., Gatilov Y. V., Zibarev A. V. Configurations of 1,3-bis(aryl)-1,3-diaza-2-thiaallenes in the crystal state // Mendeleev Communications. 1999. Vol. 9. No. 4. pp. 157-158.
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Bagryanskaya I. Y., Gatilov Y. V., Zibarev A. V. Configurations of 1,3-bis(aryl)-1,3-diaza-2-thiaallenes in the crystal state // Mendeleev Communications. 1999. Vol. 9. No. 4. pp. 157-158.
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TY - JOUR
DO - 10.1070/MC1999v009n04ABEH001140
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001140
TI - Configurations of 1,3-bis(aryl)-1,3-diaza-2-thiaallenes in the crystal state
T2 - Mendeleev Communications
AU - Bagryanskaya, Irina Yur'evna
AU - Gatilov, Yuriy Vasil'evich
AU - Zibarev, Andrey Viktorovich
PY - 1999
DA - 1999/07/09
PB - Mendeleev Communications
SP - 157-158
IS - 4
VL - 9
ER -
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@article{1999_Bagryanskaya,
author = {Irina Yur'evna Bagryanskaya and Yuriy Vasil'evich Gatilov and Andrey Viktorovich Zibarev},
title = {Configurations of 1,3-bis(aryl)-1,3-diaza-2-thiaallenes in the crystal state},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001140},
number = {4},
pages = {157--158},
doi = {10.1070/MC1999v009n04ABEH001140}
}
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Bagryanskaya, Irina Yur'evna, et al. “Configurations of 1,3-bis(aryl)-1,3-diaza-2-thiaallenes in the crystal state.” Mendeleev Communications, vol. 9, no. 4, Jul. 1999, pp. 157-158. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001140.

Abstract

The σ,π-mixing responsible for the Z,Z configuration of the title compounds is indifferent to both withdrawing (NO2) and releasing (OMe) π-electron character of ortho-substituents, and the arrangement of aromatic rings in the Z,E configuration orthogonally to the NSN plane is a universal way to overcome steric hindrances due to bulky (But, Br) ortho-substituents.

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