Home / Publications / Synthesis and regioselective cycloaddition reactions of 2,4,6-triazido-3,5-dichloropyridine

Synthesis and regioselective cycloaddition reactions of 2,4,6-triazido-3,5-dichloropyridine

Sergei Viktorovich Chapyshev 1
Sergei Viktorovich Chapyshev
10.1070/MC1999v009n04ABEH001129
Published 1999-07-09
Communication , Volume 9, Issue 4, 164-166
33
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Chapyshev S. V. Synthesis and regioselective cycloaddition reactions of 2,4,6-triazido-3,5-dichloropyridine // Mendeleev Communications. 1999. Vol. 9. No. 4. pp. 164-166.
GOST all authors (up to 50) Copy
Chapyshev S. V. Synthesis and regioselective cycloaddition reactions of 2,4,6-triazido-3,5-dichloropyridine // Mendeleev Communications. 1999. Vol. 9. No. 4. pp. 164-166.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1999v009n04ABEH001129
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001129
TI - Synthesis and regioselective cycloaddition reactions of 2,4,6-triazido-3,5-dichloropyridine
T2 - Mendeleev Communications
AU - Chapyshev, Sergei Viktorovich
PY - 1999
DA - 1999/07/09
PB - Mendeleev Communications
SP - 164-166
IS - 4
VL - 9
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1999_Chapyshev,
author = {Sergei Viktorovich Chapyshev},
title = {Synthesis and regioselective cycloaddition reactions of 2,4,6-triazido-3,5-dichloropyridine},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001129},
number = {4},
pages = {164--166},
doi = {10.1070/MC1999v009n04ABEH001129}
}
MLA
Cite this
MLA Copy
Chapyshev, Sergei Viktorovich. “Synthesis and regioselective cycloaddition reactions of 2,4,6-triazido-3,5-dichloropyridine.” Mendeleev Communications, vol. 9, no. 4, Jul. 1999, pp. 164-166. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001129.

Abstract

2,4,6-Triazido-3,5-dichloropyridine, obtained by the reaction of pentachloropyridine with sodium azide, readily adds two molecules of dimethyl acetylenedicarboxylate to the azide groups at the 2- and 6-positions, whereas, in the reaction with norbornene, it forms a cycloadduct only at the azido group in the 4-position.

References

2.
10.1070/MC1999v009n04ABEH001129_bib1_2
Chapyshev
Khim. Geterotsikl. Soedin., 1993
3.
10.1070/MC1999v009n04ABEH001129_bib1_3
Chapyshev
Khim. Geterotsikl. Soedin., 1996
4.
10.1070/MC1999v009n04ABEH001129_bib1_4
Chapyshev
Khim. Geterotsikl. Soedin., 1997
5.
10.1070/MC1999v009n04ABEH001129_bib1_5
Chapyshev
Khim. Geterotsikl. Soedin., 1997
6.
ORGANOMETALLOIDAL DERIVATIVES OF THE TRANSITION METALS I
Pannell K.H., Crawford G.M.
Journal of Coordination Chemistry, 1973
7.
C. E. Pannell, US Patent, 3883542, C07d, 1975 (Chem. Abstr., 1975, 83, 58670y).
8.
The synthesis and reactions of some polychloroaromatic azides, sulphonyl azides and sulphonohydrazides
Bernard I., Chivers G., Cremlyn R., Mootoosamy K.
Australian Journal of Chemistry, 1974
9.
Addition of aryl nitrenes to olefins
Abramovitch R.A., Challand S.R., Yamada Y.
Journal of Organic Chemistry, 1975
10.
Optimization of parameters for semiempirical methods I. Method
Stewart J.J.
Journal of Computational Chemistry, 1989
11.
Spartan version 4.0, Wavefunction, Inc., USA, 1995.
12.
10.1070/MC1999v009n04ABEH001129_bib4
Fujimoto
Chemical Reactivity and Reaction Paths, 1974
13.
10.1070/MC1999v009n04ABEH001129_bib5
Lwowski
1984
14.
Frontier molecular orbital theory of cycloaddition reactions
Houk K.N.
Accounts of Chemical Research, 1975
18.
(.pi.* + .sigma.*) Molecular orbital mixing in .beta.-chloro ketones and .beta.-chloro olefins
Morrison H., Singh T.V., De Cardenas L., Severance D., Jordan K., Schaefer W.
Journal of the American Chemical Society, 1986