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Chirality-directed co-crystallization of different configurationally opposite dialkyl 2,5-diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylates

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Kostyanovsky R. G., Lyssenko K. A., Lenev D. A. Chirality-directed co-crystallization of different configurationally opposite dialkyl 2,5-diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylates // Mendeleev Communications. 1999. Vol. 9. No. 4. pp. 154-156.
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Kostyanovsky R. G., Lyssenko K. A., Lenev D. A. Chirality-directed co-crystallization of different configurationally opposite dialkyl 2,5-diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylates // Mendeleev Communications. 1999. Vol. 9. No. 4. pp. 154-156.
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TY - JOUR
DO - 10.1070/MC1999v009n04ABEH001120
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001120
TI - Chirality-directed co-crystallization of different configurationally opposite dialkyl 2,5-diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylates
T2 - Mendeleev Communications
AU - Kostyanovsky, Remir Grigorevich
AU - Lyssenko, Konstantin Alexandrovich
AU - Lenev, Denis Alekseevich
PY - 1999
DA - 1999/07/09
PB - Mendeleev Communications
SP - 154-156
IS - 4
VL - 9
ER -
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@article{1999_Kostyanovsky,
author = {Remir Grigorevich Kostyanovsky and Konstantin Alexandrovich Lyssenko and Denis Alekseevich Lenev},
title = {Chirality-directed co-crystallization of different configurationally opposite dialkyl 2,5-diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylates},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001120},
number = {4},
pages = {154--156},
doi = {10.1070/MC1999v009n04ABEH001120}
}
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Kostyanovsky, Remir Grigorevich, et al. “Chirality-directed co-crystallization of different configurationally opposite dialkyl 2,5-diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylates.” Mendeleev Communications, vol. 9, no. 4, Jul. 1999, pp. 154-156. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001120.

Abstract

The title procedure gives quasi-racemic optically active (CD) co-crystals of 4 (space group P21) and 5 of the 1:1 composition; in [CD(–)230]-4, molecules of (–)-1 and (+)-2 are joined by amide H-bonds into infinite linear zigzag tapes packed as infinite columns.

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