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Kinetic isotope effects in the activation of H–H bonds by palladium clusters

Viktor Mikhailovich Mamaev 1
Viktor Mikhailovich Mamaev
,  , 
Andrei Viktorovich Prisyajnuk 2
Andrei Viktorovich Prisyajnuk
, 
Yurii Vladimirovich Babin 3
Yurii Vladimirovich Babin
10.1070/MC1999v009n04ABEH001094
Published 1999-07-09
Communication , Volume 9, Issue 4, 136-139
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Mamaev V. M. et al. Kinetic isotope effects in the activation of H–H bonds by palladium clusters // Mendeleev Communications. 1999. Vol. 9. No. 4. pp. 136-139.
GOST all authors (up to 50) Copy
Mamaev V. M., Gloriozov I. P., Prisyajnuk A. V., Babin Y. V. Kinetic isotope effects in the activation of H–H bonds by palladium clusters // Mendeleev Communications. 1999. Vol. 9. No. 4. pp. 136-139.
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TY - JOUR
DO - 10.1070/MC1999v009n04ABEH001094
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001094
TI - Kinetic isotope effects in the activation of H–H bonds by palladium clusters
T2 - Mendeleev Communications
AU - Mamaev, Viktor Mikhailovich
AU - Gloriozov, Igor Pavlovich
AU - Prisyajnuk, Andrei Viktorovich
AU - Babin, Yurii Vladimirovich
PY - 1999
DA - 1999/07/09
PB - Mendeleev Communications
SP - 136-139
IS - 4
VL - 9
ER -
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@article{1999_Mamaev,
author = {Viktor Mikhailovich Mamaev and Igor Pavlovich Gloriozov and Andrei Viktorovich Prisyajnuk and Yurii Vladimirovich Babin},
title = {Kinetic isotope effects in the activation of H–H bonds by palladium clusters},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001094},
number = {4},
pages = {136--139},
doi = {10.1070/MC1999v009n04ABEH001094}
}
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Mamaev, Viktor Mikhailovich, et al. “Kinetic isotope effects in the activation of H–H bonds by palladium clusters.” Mendeleev Communications, vol. 9, no. 4, Jul. 1999, pp. 136-139. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n04ABEH001094.
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Abstract

The mechanism of oxidative dihydrogen addition to palladium clusters has been analysed in terms of the reaction-path Hamiltonian approximation, and the abnormal H/D kinetic isotope effect has been explained.

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