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2,5-Diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylic acids: synthesis, resolution, absolute configuration and crystal structures of the racemic and (–)-enantiomeric forms

Remir Grigorevich Kostyanovsky 1
Remir Grigorevich Kostyanovsky
, 
Yuri Il'ich Èl'natanov 1
Yuri Il'ich Èl'natanov
, 
Oleg Nikolaevich Krutius 1
Oleg Nikolaevich Krutius
, 
Konstantin Alexandrovich Lyssenko 2
Konstantin Alexandrovich Lyssenko
, 
Ivan Ivanovich Chervin 1
Ivan Ivanovich Chervin
, 
Denis Alekseevich Lenev 3
Denis Alekseevich Lenev
10.1070/MC1999v009n03ABEH001090
Published 1999-05-27
Communication , Volume 9, Issue 3, 109-111
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Kostyanovsky R. G. et al. 2,5-Diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylic acids: synthesis, resolution, absolute configuration and crystal structures of the racemic and (–)-enantiomeric forms // Mendeleev Communications. 1999. Vol. 9. No. 3. pp. 109-111.
GOST all authors (up to 50) Copy
Kostyanovsky R. G., Èl'natanov Y. I., Krutius O. N., Lyssenko K. A., Chervin I. I., Lenev D. A. 2,5-Diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylic acids: synthesis, resolution, absolute configuration and crystal structures of the racemic and (–)-enantiomeric forms // Mendeleev Communications. 1999. Vol. 9. No. 3. pp. 109-111.
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TY - JOUR
DO - 10.1070/MC1999v009n03ABEH001090
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n03ABEH001090
TI - 2,5-Diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylic acids: synthesis, resolution, absolute configuration and crystal structures of the racemic and (–)-enantiomeric forms
T2 - Mendeleev Communications
AU - Kostyanovsky, Remir Grigorevich
AU - Èl'natanov, Yuri Il'ich
AU - Krutius, Oleg Nikolaevich
AU - Lyssenko, Konstantin Alexandrovich
AU - Chervin, Ivan Ivanovich
AU - Lenev, Denis Alekseevich
PY - 1999
DA - 1999/05/27
PB - Mendeleev Communications
SP - 109-111
IS - 3
VL - 9
ER -
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@article{1999_Kostyanovsky,
author = {Remir Grigorevich Kostyanovsky and Yuri Il'ich Èl'natanov and Oleg Nikolaevich Krutius and Konstantin Alexandrovich Lyssenko and Ivan Ivanovich Chervin and Denis Alekseevich Lenev},
title = {2,5-Diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylic acids: synthesis, resolution, absolute configuration and crystal structures of the racemic and (–)-enantiomeric forms},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n03ABEH001090},
number = {3},
pages = {109--111},
doi = {10.1070/MC1999v009n03ABEH001090}
}
MLA
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Kostyanovsky, Remir Grigorevich, et al. “2,5-Diazabicyclo[2.2.2]octane-3,6-dione-1,4-dicarboxylic acids: synthesis, resolution, absolute configuration and crystal structures of the racemic and (–)-enantiomeric forms.” Mendeleev Communications, vol. 9, no. 3, May. 1999, pp. 109-111. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n03ABEH001090.

Abstract

Title dilactam diacid 1 has been synthesised and resolved into enantiomers via diastereomeric salts 2 with a chiral amine; the absolute configuration of (1R,4R)-(–)-1 was established by decarboxylation and transformation into the parent dilactam (1R,4R)-(–)-C ; the molecular and crystal structures of (±)-1 and (–)-1 (space groups P21/n and P21, respectively) were determined.

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