Home / Publications / Reaction of 2,2-dibromotricyclo[7.1.01,9.01,3]decane with methyllithium: synthesis of bicyclo[7.1.0]decadiene-1,2 and dibromotriangulane rearrangement

Reaction of 2,2-dibromotricyclo[7.1.01,9.01,3]decane with methyllithium: synthesis of bicyclo[7.1.0]decadiene-1,2 and dibromotriangulane rearrangement

Elena Borisovna Averina 1
Elena Borisovna Averina
, 
Tamara Stepanovna Kuznetsova 1
Tamara Stepanovna Kuznetsova
, 
Alexey Nikolaevich Zefirov 1
Alexey Nikolaevich Zefirov
, 
Alexey Evgenievich Koposov 2
Alexey Evgenievich Koposov
,  , 
Nikolai Serafimovich Zefirov 1
Nikolai Serafimovich Zefirov
10.1070/MC1999v009n03ABEH001078
Published 1999-05-27
Communication , Volume 9, Issue 3, 101-102
7
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Averina E. B. et al. Reaction of 2,2-dibromotricyclo[7.1.01,9.01,3]decane with methyllithium: synthesis of bicyclo[7.1.0]decadiene-1,2 and dibromotriangulane rearrangement // Mendeleev Communications. 1999. Vol. 9. No. 3. pp. 101-102.
GOST all authors (up to 50) Copy
Averina E. B., Kuznetsova T. S., Zefirov A. N., Koposov A. E., Grishin Y. K., Zefirov N. S. Reaction of 2,2-dibromotricyclo[7.1.01,9.01,3]decane with methyllithium: synthesis of bicyclo[7.1.0]decadiene-1,2 and dibromotriangulane rearrangement // Mendeleev Communications. 1999. Vol. 9. No. 3. pp. 101-102.
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TY - JOUR
DO - 10.1070/MC1999v009n03ABEH001078
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n03ABEH001078
TI - Reaction of 2,2-dibromotricyclo[7.1.01,9.01,3]decane with methyllithium: synthesis of bicyclo[7.1.0]decadiene-1,2 and dibromotriangulane rearrangement
T2 - Mendeleev Communications
AU - Averina, Elena Borisovna
AU - Kuznetsova, Tamara Stepanovna
AU - Zefirov, Alexey Nikolaevich
AU - Koposov, Alexey Evgenievich
AU - Grishin, Yuri Konstantinovich
AU - Zefirov, Nikolai Serafimovich
PY - 1999
DA - 1999/05/27
PB - Mendeleev Communications
SP - 101-102
IS - 3
VL - 9
ER -
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@article{1999_Averina,
author = {Elena Borisovna Averina and Tamara Stepanovna Kuznetsova and Alexey Nikolaevich Zefirov and Alexey Evgenievich Koposov and Yuri Konstantinovich Grishin and Nikolai Serafimovich Zefirov},
title = {Reaction of 2,2-dibromotricyclo[7.1.01,9.01,3]decane with methyllithium: synthesis of bicyclo[7.1.0]decadiene-1,2 and dibromotriangulane rearrangement},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n03ABEH001078},
number = {3},
pages = {101--102},
doi = {10.1070/MC1999v009n03ABEH001078}
}
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Averina, Elena Borisovna, et al. “Reaction of 2,2-dibromotricyclo[7.1.01,9.01,3]decane with methyllithium: synthesis of bicyclo[7.1.0]decadiene-1,2 and dibromotriangulane rearrangement.” Mendeleev Communications, vol. 9, no. 3, May. 1999, pp. 101-102. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n03ABEH001078.

Abstract

Reaction of 2,2-dibromotricyclo[7.1.01,9.01,3]decane with methyllithium gives strained cyclic allene 1 containing an ethenylidenecyclopropane unit in a nine-membered ring and dimer 6 resulting from a dibromotriangulane rearrangement.

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