Home / Publications / Synthesis and structure of stable chiral AuI complexes with N,N′-diaryl-α-naphthamidinium-N′-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl] ylides

Synthesis and structure of stable chiral AuI complexes with N,N′-diaryl-α-naphthamidinium-N′-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl] ylides

Galina Anatol'evna Dushenko 1
Galina Anatol'evna Dushenko
, 
Igor Evguen'evich Mikhailov 1
Igor Evguen'evich Mikhailov
, 
Adolf Zschunke 2
Adolf Zschunke
, 
Gunter Reck 2
Gunter Reck
, 
Burkhard Schulz 2
Burkhard Schulz
, 
Clemens Muegge 3
Clemens Muegge
, 
Vladimir Isaakovich Minkin 1
Vladimir Isaakovich Minkin
10.1070/MC1999v009n02ABEH001064
Published 1999-04-01
Communication , Volume 9, Issue 2, 67-70
8
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Dushenko G. A. et al. Synthesis and structure of stable chiral AuI complexes with N,N′-diaryl-α-naphthamidinium-N′-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl] ylides // Mendeleev Communications. 1999. Vol. 9. No. 2. pp. 67-70.
GOST all authors (up to 50) Copy
Dushenko G. A., Mikhailov I. E., Zschunke A., Reck G., Schulz B., Muegge C., Minkin V. I. Synthesis and structure of stable chiral AuI complexes with N,N′-diaryl-α-naphthamidinium-N′-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl] ylides // Mendeleev Communications. 1999. Vol. 9. No. 2. pp. 67-70.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1999v009n02ABEH001064
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n02ABEH001064
TI - Synthesis and structure of stable chiral AuI complexes with N,N′-diaryl-α-naphthamidinium-N′-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl] ylides
T2 - Mendeleev Communications
AU - Dushenko, Galina Anatol'evna
AU - Mikhailov, Igor Evguen'evich
AU - Zschunke, Adolf
AU - Reck, Gunter
AU - Schulz, Burkhard
AU - Muegge, Clemens
AU - Minkin, Vladimir Isaakovich
PY - 1999
DA - 1999/04/01
PB - Mendeleev Communications
SP - 67-70
IS - 2
VL - 9
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1999_Dushenko,
author = {Galina Anatol'evna Dushenko and Igor Evguen'evich Mikhailov and Adolf Zschunke and Gunter Reck and Burkhard Schulz and Clemens Muegge and Vladimir Isaakovich Minkin},
title = {Synthesis and structure of stable chiral AuI complexes with N,N′-diaryl-α-naphthamidinium-N′-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl] ylides},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n02ABEH001064},
number = {2},
pages = {67--70},
doi = {10.1070/MC1999v009n02ABEH001064}
}
MLA
Cite this
MLA Copy
Dushenko, Galina Anatol'evna, et al. “Synthesis and structure of stable chiral AuI complexes with N,N′-diaryl-α-naphthamidinium-N′-[2,3,4,5-tetra(methoxycarbonyl)cyclopentadien-1-yl] ylides.” Mendeleev Communications, vol. 9, no. 2, Apr. 1999, pp. 67-70. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n02ABEH001064.

Abstract

Novel N-amidine-functionalized cyclopentadiene gold(I) complexes [C5(CO2Me)4{ArNC(α-C10H7)NAr}]Au(PPh3) have been prepared, and their stable chiral structure with the Au–N bond [2.091(6) Å] and the additional coordination Au···π-system of the cyclopentadiene ring has been proved by X-ray crystallography and NMR spectroscopy.

References

3.
Cyclopentadienyl compounds with nitrogen donors in the side-chain
Jutzi P., Siemeling U.
Journal of Organometallic Chemistry, 1995
4.
Novel chiral Lewis acids based on a new asymmetric cyclopentadienyl ligand
van der Zeijden A.A.
Journal of Organometallic Chemistry, 1996
6.
Dushenko G.A., Mikhailov I.E., Kompan O.E., Zschunke A., Reck G., Schulz B., Mugge C., Minkin V.I.
Mendeleev Communications, 1997
7.
10.1070/MC1999v009n02ABEH001064_bib7
Oszczapowicz
The Chemistry of Amidines and Imidates, 1991
8.
Three- and Four-Coordinate Gold(I) Complexes
Gimeno M.C., Laguna A.
Chemical Reviews, 1997
10.
10.1070/MC1999v009n02ABEH001064_bib10
Minkin
J. Chem. Soc., Chem. Commun., 1988
11.
New organogold(I) complexes: Synthesis, structure, and dynamic behavior of the polynuclear organogold diphenylmethane and diphenylethane derivatives
Baukova T.V., Kuz'mina L.G., Oleinikova N.A., Lemenovskii D.A., Blumenfel'd A.L.
Journal of Organometallic Chemistry, 1997
12.
Ludwig Mond Lecture. High-carat gold compounds
Schmidbaur H.
Chemical Society Reviews, 1995
15.
Characteristic structural features of post-transition metal cyclopentadienyl derivatives
Baukova T.V., Slovokhotov Y.L., Struchkov Y.T.
Journal of Organometallic Chemistry, 1981
16.
Pentabenzylcyclopentadienyl(triphenylphosphan)gold(I)
Schumann H., Görlitz F.H., Dietrich A.
Chemische Berichte, 1989
17.
1,5‐Sigmatropic shifts of bromine over a cyclopentadiene ring
Minkin V.I., Mikhailov I.E., Dushenko G.A., Yudilevich J.A., Minyaev R.M., Zschunke A., Mögge K.
Journal of Physical Organic Chemistry, 1991