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Structure and conformation of tri-O-acetyl-D-glucal dimer in solid state and in solution

Andreas H Franz 1
Andreas H Franz
,  , 
Vyacheslav Vladimirovich Samoshin 1
Vyacheslav Vladimirovich Samoshin
, 
Michael J Minch 1
Michael J Minch
, 
Victor G YoungJr 3
Victor G YoungJr
, 
Paul H Gross 1
Paul H Gross
10.1070/MC1999v009n02ABEH001061
Published 1999-04-01
Communication , Volume 9, Issue 2, 45-47
3
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Franz A. H. et al. Structure and conformation of tri-O-acetyl-D-glucal dimer in solid state and in solution // Mendeleev Communications. 1999. Vol. 9. No. 2. pp. 45-47.
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Franz A. H., Zhdankin V. V., Samoshin V. V., Minch M. J., YoungJr V. G., Gross P. H. Structure and conformation of tri-O-acetyl-D-glucal dimer in solid state and in solution // Mendeleev Communications. 1999. Vol. 9. No. 2. pp. 45-47.
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TY - JOUR
DO - 10.1070/MC1999v009n02ABEH001061
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n02ABEH001061
TI - Structure and conformation of tri-O-acetyl-D-glucal dimer in solid state and in solution
T2 - Mendeleev Communications
AU - Franz, Andreas H
AU - Zhdankin, Viktor Vladimirovich
AU - Samoshin, Vyacheslav Vladimirovich
AU - Minch, Michael J
AU - YoungJr, Victor G
AU - Gross, Paul H
PY - 1999
DA - 1999/04/01
PB - Mendeleev Communications
SP - 45-47
IS - 2
VL - 9
ER -
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@article{1999_Franz,
author = {Andreas H Franz and Viktor Vladimirovich Zhdankin and Vyacheslav Vladimirovich Samoshin and Michael J Minch and Victor G YoungJr and Paul H Gross},
title = {Structure and conformation of tri-O-acetyl-D-glucal dimer in solid state and in solution},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n02ABEH001061},
number = {2},
pages = {45--47},
doi = {10.1070/MC1999v009n02ABEH001061}
}
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Franz, Andreas H., et al. “Structure and conformation of tri-O-acetyl-D-glucal dimer in solid state and in solution.” Mendeleev Communications, vol. 9, no. 2, Apr. 1999, pp. 45-47. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n02ABEH001061.

Abstract

X-Ray crystallography and 1H NMR spectroscopy indicate that the conformations of both rings A and B and the relative orientation of the rings in the C-linked disaccharide 1,3,4,6-tetra-O-acetyl-2-C-(4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2- enopyranosyl)-2-deoxy-β-D-glucopyranose in solution are virtually identical to the crystalline structure.

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