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EPR study of the reaction of C60 with chlorine dioxide: experimental evidence for the formation of the C60 radical cation

Vyacheslav Ivanovich Sokolov 1
Vyacheslav Ivanovich Sokolov
Vasily Vasilevich Bashilov 1
Vasily Vasilevich Bashilov
Qadir Kamilevich Timerghazin 2
Qadir Kamilevich Timerghazin
Elena Vil'evna Avzyanova 2
Elena Vil'evna Avzyanova
Alexey Fedorovich Khalizov 2
Alexey Fedorovich Khalizov
Nikolay Mikhailovich Shishlov 2
Nikolay Mikhailovich Shishlov
Valerii Vladimirovich Shereshovets 2
Valerii Vladimirovich Shereshovets
Published 1999-04-01
CommunicationVolume 9, Issue 2, 54-55
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Sokolov V. I. et al. EPR study of the reaction of C60 with chlorine dioxide: experimental evidence for the formation of the C60 radical cation // Mendeleev Communications. 1999. Vol. 9. No. 2. pp. 54-55.
GOST all authors (up to 50) Copy
Sokolov V. I., Bashilov V. V., Timerghazin Q. K., Avzyanova E. V., Khalizov A. F., Shishlov N. M., Shereshovets V. V. EPR study of the reaction of C60 with chlorine dioxide: experimental evidence for the formation of the C60 radical cation // Mendeleev Communications. 1999. Vol. 9. No. 2. pp. 54-55.
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TY - JOUR
DO - 10.1070/MC1999v009n02ABEH001046
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n02ABEH001046
TI - EPR study of the reaction of C60 with chlorine dioxide: experimental evidence for the formation of the C60 radical cation
T2 - Mendeleev Communications
AU - Sokolov, Vyacheslav Ivanovich
AU - Bashilov, Vasily Vasilevich
AU - Timerghazin, Qadir Kamilevich
AU - Avzyanova, Elena Vil'evna
AU - Khalizov, Alexey Fedorovich
AU - Shishlov, Nikolay Mikhailovich
AU - Shereshovets, Valerii Vladimirovich
PY - 1999
DA - 1999/04/01
PB - Mendeleev Communications
SP - 54-55
IS - 2
VL - 9
ER -
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@article{1999_Sokolov,
author = {Vyacheslav Ivanovich Sokolov and Vasily Vasilevich Bashilov and Qadir Kamilevich Timerghazin and Elena Vil'evna Avzyanova and Alexey Fedorovich Khalizov and Nikolay Mikhailovich Shishlov and Valerii Vladimirovich Shereshovets},
title = {EPR study of the reaction of C60 with chlorine dioxide: experimental evidence for the formation of the C60 radical cation},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n02ABEH001046},
number = {2},
pages = {54--55},
doi = {10.1070/MC1999v009n02ABEH001046}
}
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Sokolov, Vyacheslav Ivanovich, et al. “EPR study of the reaction of C60 with chlorine dioxide: experimental evidence for the formation of the C60 radical cation.” Mendeleev Communications, vol. 9, no. 2, Apr. 1999, pp. 54-55. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n02ABEH001046.

Abstract

The interaction of chlorine dioxide with fullerene C60 affords a brown precipitate, and its EPR spectrum exhibits an asymmetric singlet signal (g = 2.0029, ΔHpp = 0.2 mT) tentatively assigned to the fullerene radical cation.

References

1.
Solid C60: a new form of carbon
Krätschmer W., Lamb L.D., Fostiropoulos K., Huffman D.R.
Nature, 1990
2.
Spectroelectrochemical study of the C60 and C70 fullerenes and their mono-, di-, tri- and tetraanions
Dubois D., Kadish K.M., Flanagan S., Haufler R.E., Chibante L.P., Wilson L.J.
Journal of the American Chemical Society, 1991
4.
Production of fullerene (C60) radical cation by photosensitized electron transfer
Nonell S., Arbogast J.W., Foote C.S.
The Journal of Physical Chemistry, 1992
5.
Photoinduced Electron Transfer from Triplet Fullerene, 3C60, to Tetracyanoethylene. Fourier Transform Electron Paramagnetic Resonance Study
6.
Addition of Alcohols and Hydrocarbons to Fullerenes by Photosensitized Electron Transfer
Lem G., Schuster D.I., Courtney S.H., Lu Q., Wilson S.R.
Journal of the American Chemical Society, 1995
7.
Laser Flash Photolysis Study on Photochemical Generation of Radical Cations of Fullerenes C60, C70, and C76
Fujitsuka M., Watanabe A., Ito O., Yamamoto K., Funasaka H.
Journal of Physical Chemistry A, 1997
8.
Disproportionation of Photoexcited C60
Yang C.C., Hwang K.C.
Journal of the American Chemical Society, 1996
9.
W. J. Masschelin, R. G. Rice. Chlorine Dioxide, Chemistry and Environmental Impact of Oxychlorine Compounds, Ann Arbor Science, Ann Arbor, 1979.
10.
The Chemistry of Chlorine Dioxide
Gordon G., Kieffer R.G., Rosenblatt D.H.
Progress in Inorganic Chemistry, 1972
11.
10.1070/MC1999v009n02ABEH001046_bib11
Troitskaya
Zh. Fiz. Khim., 1959
13.
Electrochemical detection of fulleronium and highly reduced fulleride (C605-) ions in solution
Dubois D., Kadish K.M., Flanagan S., Wilson L.J.
Journal of the American Chemical Society, 1991
14.
Apparent absence of Pauli paramagnetism in metallic polyparaphenylene
Peo M., Roth S., Dransfeld K., Tieke B., Hocker J., Gross H., Grupp A., Sixl H.
Solid State Communications, 1980
15.
ESR studies of poly(phthalidylidenearylene)s doped with iodine
Shishlov N.M., Novoselov I.V., Zolotukhin M.G.
Synthetic Metals, 1997