Home / Publications / Recyclization of 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyl- tetrahydro-4-pyrone oximes to 5-amino- and 5-methylamino-5-trifluoromethyl-3-(2-hydroxy-1,1-dimethylethyl)-Δ2-isoxazolines

Recyclization of 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyl- tetrahydro-4-pyrone oximes to 5-amino- and 5-methylamino-5-trifluoromethyl-3-(2-hydroxy-1,1-dimethylethyl)-Δ2-isoxazolines

Vyacheslav Yakovlevich Sosnovskikh 1
Vyacheslav Yakovlevich Sosnovskikh
, 
Mikhail Yur'evich Mel'nikov 1
Mikhail Yur'evich Mel'nikov
, 
Andrei Victorovich Zaitsev 1
Andrei Victorovich Zaitsev
10.1070/MC1999v009n01ABEH001049
Published 1999-02-16
Communication , Volume 9, Issue 1, 40-41
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Sosnovskikh V. Y., Mel'nikov M. Y., Zaitsev A. V. Recyclization of 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyl- tetrahydro-4-pyrone oximes to 5-amino- and 5-methylamino-5-trifluoromethyl-3-(2-hydroxy-1,1-dimethylethyl)-Δ2-isoxazolines // Mendeleev Communications. 1999. Vol. 9. No. 1. pp. 40-41.
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Sosnovskikh V. Y., Mel'nikov M. Y., Zaitsev A. V. Recyclization of 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyl- tetrahydro-4-pyrone oximes to 5-amino- and 5-methylamino-5-trifluoromethyl-3-(2-hydroxy-1,1-dimethylethyl)-Δ2-isoxazolines // Mendeleev Communications. 1999. Vol. 9. No. 1. pp. 40-41.
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TY - JOUR
DO - 10.1070/MC1999v009n01ABEH001049
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n01ABEH001049
TI - Recyclization of 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyl- tetrahydro-4-pyrone oximes to 5-amino- and 5-methylamino-5-trifluoromethyl-3-(2-hydroxy-1,1-dimethylethyl)-Δ2-isoxazolines
T2 - Mendeleev Communications
AU - Sosnovskikh, Vyacheslav Yakovlevich
AU - Mel'nikov, Mikhail Yur'evich
AU - Zaitsev, Andrei Victorovich
PY - 1999
DA - 1999/02/16
PB - Mendeleev Communications
SP - 40-41
IS - 1
VL - 9
ER -
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@article{1999_Sosnovskikh,
author = {Vyacheslav Yakovlevich Sosnovskikh and Mikhail Yur'evich Mel'nikov and Andrei Victorovich Zaitsev},
title = {Recyclization of 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyl- tetrahydro-4-pyrone oximes to 5-amino- and 5-methylamino-5-trifluoromethyl-3-(2-hydroxy-1,1-dimethylethyl)-Δ2-isoxazolines},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n01ABEH001049},
number = {1},
pages = {40--41},
doi = {10.1070/MC1999v009n01ABEH001049}
}
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Sosnovskikh, Vyacheslav Yakovlevich, et al. “Recyclization of 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyl- tetrahydro-4-pyrone oximes to 5-amino- and 5-methylamino-5-trifluoromethyl-3-(2-hydroxy-1,1-dimethylethyl)-Δ2-isoxazolines.” Mendeleev Communications, vol. 9, no. 1, Feb. 1999, pp. 40-41. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n01ABEH001049.

Abstract

The reactions of hydroxylamine with 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyltetrahydro-4-pyrones yield 2-amino- and 2-methylamino-2-trifluoromethyl-5,5-dimethyltetrahydro-4-pyrone oximes, which can be converted to 5-amino- and 5-methylamino-5-trifluoromethyl-3-(2-hydroxy-1,1-dimethylethyl)-Δ2-isoxazolines, respectively, by heating in ethanol.

References

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V. Ya. Sosnovskikh, S. A. Pogozhikh and M. Yu. Mel’nikov, Izv. Akad. Nauk, Ser. Khim., in press.
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